抄録
The DNA cleavage via superoxide anion, formed in photoinduced electron transfer from NADH to γ-cyclodextrin-bicapped C60 in a oxygen-saturated aqueous solution, was discussed. The reorganization energy for the reduction of O2 to O2.- was found to be 43.4 Kcal mol-1. The analysis suggested that the electron transfer from C60.-/γ-CyD to O2 proceeded via an outer sphere pathway.
本文言語 | English |
---|---|
ページ(範囲) | 2372-2380 |
ページ数 | 9 |
ジャーナル | Journal of Physical Chemistry B |
巻 | 106 |
号 | 9 |
DOI | |
出版ステータス | Published - 2002 3月 7 |
外部発表 | はい |
ASJC Scopus subject areas
- 物理化学および理論化学
- 表面、皮膜および薄膜
- 材料化学