Effect of potassium polyvinyl sulfate on the separation of Alkali metal and alkaline earth metal ions by capillary zone electrophoresis

Takashi Masadome, Yutaka Nakaone

研究成果: Article

抄録

The effect of a soluble anionic polymer, potassium poly (vinyl sulfate) (PVSK) added to a background electrolyte (BGE) was examined for the separation of alkali and alkaline earth metal ions (Na + , K + , Ca 2+ , Mg 2+ and Sr 2+ ) by capillary electrophoresis with indirect UV detection. Creatinine was used as an UV-absorbing compound. Each alkali ion was resolved, and each divalent ion was detected as a single peak using a soluble anionic polymer added to BGE. The result shows that the separation of monovalent cations and divalent cations is possible, and that the separation of divalent cations from each other is impossible.

元の言語English
ページ(範囲)607-610
ページ数4
ジャーナルBunseki Kagaku
67
発行部数10
DOI
出版物ステータスPublished - 2018 1 1

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Alkaline Earth Metals
Alkali Metals
Electrophoresis
Metal ions
Potassium
Divalent Cations
Alkalies
Electrolytes
Polymers
Ions
Monovalent Cations
Capillary electrophoresis
Sulfates
Creatinine
polyvinyl sulfate

ASJC Scopus subject areas

  • Analytical Chemistry

これを引用

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abstract = "The effect of a soluble anionic polymer, potassium poly (vinyl sulfate) (PVSK) added to a background electrolyte (BGE) was examined for the separation of alkali and alkaline earth metal ions (Na + , K + , Ca 2+ , Mg 2+ and Sr 2+ ) by capillary electrophoresis with indirect UV detection. Creatinine was used as an UV-absorbing compound. Each alkali ion was resolved, and each divalent ion was detected as a single peak using a soluble anionic polymer added to BGE. The result shows that the separation of monovalent cations and divalent cations is possible, and that the separation of divalent cations from each other is impossible.",
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T1 - Effect of potassium polyvinyl sulfate on the separation of Alkali metal and alkaline earth metal ions by capillary zone electrophoresis

AU - Masadome, Takashi

AU - Nakaone, Yutaka

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N2 - The effect of a soluble anionic polymer, potassium poly (vinyl sulfate) (PVSK) added to a background electrolyte (BGE) was examined for the separation of alkali and alkaline earth metal ions (Na + , K + , Ca 2+ , Mg 2+ and Sr 2+ ) by capillary electrophoresis with indirect UV detection. Creatinine was used as an UV-absorbing compound. Each alkali ion was resolved, and each divalent ion was detected as a single peak using a soluble anionic polymer added to BGE. The result shows that the separation of monovalent cations and divalent cations is possible, and that the separation of divalent cations from each other is impossible.

AB - The effect of a soluble anionic polymer, potassium poly (vinyl sulfate) (PVSK) added to a background electrolyte (BGE) was examined for the separation of alkali and alkaline earth metal ions (Na + , K + , Ca 2+ , Mg 2+ and Sr 2+ ) by capillary electrophoresis with indirect UV detection. Creatinine was used as an UV-absorbing compound. Each alkali ion was resolved, and each divalent ion was detected as a single peak using a soluble anionic polymer added to BGE. The result shows that the separation of monovalent cations and divalent cations is possible, and that the separation of divalent cations from each other is impossible.

KW - Alkali ions

KW - Alkaline earth metal ions

KW - Capillary zone electrophoresis

KW - Indirect photometric method

KW - Soluble anionic polymer

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