Effect of Tl doping on the phase stability of Hg2Ba2(Y,Ca)1Cu2O 8-δ superconductors prepared by a high-pressure technique

Ayako Tokiwa-Yamamoto, Tadashi Tatsuki, Xiao Jing Wu, Seiji Adachi, Keiichi Tanabe

研究成果: Article査読

27 被引用数 (Scopus)


(Hg, T1) based cuprates with the nominal compositions of (Hg1-xT1x)2Ba2Y1-yCa yCu2O8-δ (0 ≦ x ≦ 1.0 and 0 ≦ y ≦ 1.0) were prepared under a high pressure and high temperature. The solubility of Ca ions into Ae Hg-2212 phase for various T1 contents was examined by X-ray powder diffraction and energy-dispersive X-ray spectroscopy. The substitution of Ca2+ for the Y3+ site for the samples with x = 0.3 and 0.5 is realized over a full range of 0 ≦ y ≦ 1.0, while the solubility range is limited for the samples with x ≦ 0.15 and x ≧ 0.75. The samples with x = 0.3 exhibited a maximum Tc of 84 K, which was about 30 K higher than the maximum Tc for the samples with x = 0. The significant extension of Ca solubility for the T1 doped samples is probably explained by the compensation of excess negative charges in the (Hg1-xT1x)2O2-δ charge reservoir. The fact that the Y free Hg-2212 phase is obtained by T1 doping suggests the possibility of synthesizing a Hg-22(n - 1)n (n = 3, 4, ⋯) homologous series.

ジャーナルPhysica C: Superconductivity and its applications
出版ステータスPublished - 1996 3 1

ASJC Scopus subject areas

  • 電子材料、光学材料、および磁性材料
  • 凝縮系物理学
  • エネルギー工学および電力技術
  • 電子工学および電気工学


「Effect of Tl doping on the phase stability of Hg<sub>2</sub>Ba<sub>2</sub>(Y,Ca)<sub>1</sub>Cu<sub>2</sub>O <sub>8-δ</sub> superconductors prepared by a high-pressure technique」の研究トピックを掘り下げます。これらがまとまってユニークなフィンガープリントを構成します。