Effects of metal substitution on superconductivity and crystal structure of HgBa2CuO4+δ

W. Z. Hu, A. Yamamoto, M. Izumi, S. Tajima

研究成果: Article

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High-Tc superconducting oxides with nominal compositions of HgBa2Cu1-xMxO4+δ (M=Fe, Co, Ni, Zn and Mg, x=0-0.03) were prepared, and crystal structure and substitution effects on superconducting properties were studied using X-ray powder diffraction, susceptibility and resistivity. Almost all single-phase samples were obtained for M=Fe, Co, Zn and Mg, while impurities such as Ni3Ba3O8 were detected for M=Ni. A significant decrease in Tc and an increase in lattice parameter a for the samples with Zn and Mg indicated that these metals were successfully substituted for Cu. On the other hand, there was no remarkable change in Tc for the sample with Fe and Co, which suggests a possibility of substitution for Hg. Zn- and Mg-substitution effects on superconductivity were discussed from the viewpoint of structural change, in comparison with the cases of La2-xSrxCuO4 and YBa2Cu3O6+δ.

元の言語English
ページ(範囲)141-148
ページ数8
ジャーナルPhysica C: Superconductivity and its applications
356
発行部数1-2
DOI
出版物ステータスPublished - 2001 1 7

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ASJC Scopus subject areas

  • Electronic, Optical and Magnetic Materials
  • Condensed Matter Physics
  • Energy Engineering and Power Technology
  • Electrical and Electronic Engineering

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