Electrocatalytic debromination of organic bromides using a cobalt(II)salen complex in ionic liquids

Yi Shen; Toshiki Tajima; Mahito Atobe; Toshio Fuchigami

doi:10.5796/electrochemistry.72.849

Electrocatalytic debromination of organic bromides using a cobalt(II)salen complex in ionic liquids

Yi Shen, Toshiki Tajima, Mahito Atobe, Toshio Fuchigami

研究成果: Article › 査読

9 被引用数 (Scopus)

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The catalytic effect of a Co(II)salen mediator on the reduction of cyclic vic-dibromide was investigated in ionic liquids by cyclic voltammetry. Macro-scale controlled potential electrolysis gave the corresponding debrominated product in moderate to good yields. The workup after electrolysis in an ionic liquid proved to be much simpler than that in organic solvents. The possibility of reuse of the ionic liquid was demonstrated to some extent.

本文言語	English
ページ（範囲）	849-851
ページ数	3
ジャーナル	Electrochemistry
巻	72
号	12
DOI	https://doi.org/10.5796/electrochemistry.72.849
出版ステータス	Published - 2004 12月
外部発表	はい

ASJC Scopus subject areas

電気化学

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10.5796/electrochemistry.72.849

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AB - The catalytic effect of a Co(II)salen mediator on the reduction of cyclic vic-dibromide was investigated in ionic liquids by cyclic voltammetry. Macro-scale controlled potential electrolysis gave the corresponding debrominated product in moderate to good yields. The workup after electrolysis in an ionic liquid proved to be much simpler than that in organic solvents. The possibility of reuse of the ionic liquid was demonstrated to some extent.

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Electrocatalytic debromination of organic bromides using a cobalt(II)salen complex in ionic liquids

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