Electrochemical partial fluorination of organic compounds. 80. Synthesis of cyclic α-arylthio-α-monofluorophosphonate esters

Yi Cao, Asami Hidaka, Toshiki Tajima, Toshio Fuchigami

研究成果: Article

23 引用 (Scopus)

抜粋

Seven-membered cyclic α-monofluorophosphonate esters such as 2-allyloxy-3-fluoro-3-phenylthio-4,7-dihydro-[1, 2]-oxaphosphinine-2-oxide were successfully synthesized in moderate total yield as 41% from open-chain allyl phosphonates having an α-arylthio group as an electroauxiliary using an alternative sequence of anodic fluorination and ring-closing olefin metathesis (RCM). On the other hand, in an attempt to synthesize an eight-membered analogue, a different type of seven-membered fluorinated cyclic product was formed predominantly by the RCM reaction between the allyloxy groups.

元の言語English
ページ(範囲)9614-9617
ページ数4
ジャーナルJournal of Organic Chemistry
70
発行部数23
DOI
出版物ステータスPublished - 2005 11 11
外部発表Yes

ASJC Scopus subject areas

  • Organic Chemistry

フィンガープリント Electrochemical partial fluorination of organic compounds. 80. Synthesis of cyclic α-arylthio-α-monofluorophosphonate esters' の研究トピックを掘り下げます。これらはともに一意のフィンガープリントを構成します。

  • これを引用