Electrolytic partial fluorination of organic compounds. 77. Reactivity of anodically generated benzylic cation intermediates toward fluoride ions in acetonitrile

Toshiki Tajima, Hitoshi Kurihara, Atsushi Nakajima, Toshio Fuchigami

研究成果: Article査読

6 被引用数 (Scopus)

抄録

Anodic benzylic fluorination of alkylbenzenes was comparatively studied in MeCN using Et4NF-4HF as a supporting electrolyte and a fluorine source. The anodic benzylic fluorination proceeded except for some cumene derivatives and the yields of fluorinated products greatly depended on the stability of the benzylic cation intermediates. It was found that fluoride ions reacted with more stable benzylic cations preferentially, while acetamidation took place preferentially at less stable benzylic cations.

本文言語English
ページ(範囲)155-160
ページ数6
ジャーナルJournal of Electroanalytical Chemistry
580
1
DOI
出版ステータスPublished - 2005 6月 15
外部発表はい

ASJC Scopus subject areas

  • 分析化学
  • 化学工学(全般)
  • 電気化学

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