抜粋
Anodic gem-difluorination of hydrazones in Et4NF-5HF/CH2Cl2 in the presence of Et4NI was successfully carried out to provide the corresponding gem-difluorinated products in moderate to good yields. On the other hand, no gem-difluorinated products were obtained in the absence of Et4NI. Although a catalytic current was not observed in the cyclic voltammetry of Et4NI in the presence of a hydrazone, a controlled potential electrolysis of the hydrazone showed that Et4NI acted as a mediator in the anodic gem-difluorination of hydrazones.
| 元の言語 | English |
|---|---|
| ページ（範囲） | 43-46 |
| ページ数 | 4 |
| ジャーナル | Journal of Electroanalytical Chemistry |
| 巻 | 593 |
| 発行部数 | 1-2 |
| DOI | |
| 出版物ステータス | Published - 2006 8 1 |
| 外部発表 | Yes |
ASJC Scopus subject areas
- Analytical Chemistry
- Chemical Engineering(all)
- Electrochemistry
フィンガープリント Electrolytic partial fluorination of organic compounds. Part 85. Anodic gem-difluorination of hydrazones using Et<sub>4</sub>NI as a mediator' の研究トピックを掘り下げます。これらはともに一意のフィンガープリントを構成します。
これを引用
Tajima, T., Imai, N., Nakajima, A., Kurihara, H., & Fuchigami, T. (2006). Electrolytic partial fluorination of organic compounds. Part 85. Anodic gem-difluorination of hydrazones using Et4NI as a mediator. Journal of Electroanalytical Chemistry, 593(1-2), 43-46. https://doi.org/10.1016/j.jelechem.2006.01.021