Electrolytic partial fluorination of organic compounds. Part 85. Anodic gem-difluorination of hydrazones using Et4NI as a mediator

Toshiki Tajima, Nanae Imai, Atsushi Nakajima, Hitoshi Kurihara, Toshio Fuchigami

研究成果: Article査読

4 被引用数 (Scopus)

抄録

Anodic gem-difluorination of hydrazones in Et4NF-5HF/CH2Cl2 in the presence of Et4NI was successfully carried out to provide the corresponding gem-difluorinated products in moderate to good yields. On the other hand, no gem-difluorinated products were obtained in the absence of Et4NI. Although a catalytic current was not observed in the cyclic voltammetry of Et4NI in the presence of a hydrazone, a controlled potential electrolysis of the hydrazone showed that Et4NI acted as a mediator in the anodic gem-difluorination of hydrazones.

本文言語English
ページ(範囲)43-46
ページ数4
ジャーナルJournal of Electroanalytical Chemistry
593
1-2
DOI
出版ステータスPublished - 2006 8月 1
外部発表はい

ASJC Scopus subject areas

  • 分析化学
  • 化学工学(全般)
  • 電気化学

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