Electroreductive hydrogenation of activated olefins using the concept of site isolation

Shinsuke Tomida, Ryohei Tsuda, Shiho Furukawa, Marie Saito, Toshiki Tajima

研究成果: Article

4 引用 (Scopus)

抄録

Electroreductive hydrogenation of activated olefins was investigated using the concept of site isolation. It was shown by electrochemical measurements as well as preparative electrolyses that the use of silica gel-supported sulfonic acid (Si-SO3H) promotes the protonation step in electroreductive hydrogenation of activated olefins without electroreductive destruction at the cathode. On the basis of the concept of site isolation, electroreductive hydrogenation of several activated olefins was successfully carried out to provide the corresponding hydrogenation products in high yields.

元の言語English
ページ(範囲)46-49
ページ数4
ジャーナルElectrochemistry Communications
73
DOI
出版物ステータスPublished - 2016 12 1

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Alkenes
Olefins
Hydrogenation
Sulfonic Acids
Protonation
Silica Gel
Silica gel
Electrolysis
Cathodes
Acids

ASJC Scopus subject areas

  • Electrochemistry

これを引用

Electroreductive hydrogenation of activated olefins using the concept of site isolation. / Tomida, Shinsuke; Tsuda, Ryohei; Furukawa, Shiho; Saito, Marie; Tajima, Toshiki.

:: Electrochemistry Communications, 巻 73, 01.12.2016, p. 46-49.

研究成果: Article

Tomida, Shinsuke ; Tsuda, Ryohei ; Furukawa, Shiho ; Saito, Marie ; Tajima, Toshiki. / Electroreductive hydrogenation of activated olefins using the concept of site isolation. :: Electrochemistry Communications. 2016 ; 巻 73. pp. 46-49.
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AU - Tajima, Toshiki

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KW - Site isolation

KW - Solid-supported acid

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