Enantiodifferentiating photocyclodimerization of 2-anthracenecarboxylic acid mediated by γ-cyclodextrins with a flexible or rigid cap

Cheng Yang, Asao Nakamura, Takehiko Wada, Yoshihisa Inoue

研究成果: Article

61 引用 (Scopus)

抄録

A series of modified γ-cyclodextrins (CDs) with a flexible or rigid cap, synthesized and used as chiral supramolecular hosts for mediating the enantiodifferentiating photocyclodimerization of 2-anthracenecarboxylic acid, significantly improved the chemical and optical yields of chiral head-to-head cyclodimer 3, while the γ-CD with a rigid cap dramatically inverted the stereochemical outcomes and further improved the enantioselectivities of both head-to-tail and head-to-head dimers 2 and 3.

元の言語English
ページ(範囲)3005-3008
ページ数4
ジャーナルOrganic Letters
8
発行部数14
DOI
出版物ステータスPublished - 2006 7 6
外部発表Yes

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Cyclodextrins
caps
acids
Enantioselectivity
Dimers
dimers
anthracene-1-carboxylic acid

ASJC Scopus subject areas

  • Molecular Medicine

これを引用

Enantiodifferentiating photocyclodimerization of 2-anthracenecarboxylic acid mediated by γ-cyclodextrins with a flexible or rigid cap. / Yang, Cheng; Nakamura, Asao; Wada, Takehiko; Inoue, Yoshihisa.

:: Organic Letters, 巻 8, 番号 14, 06.07.2006, p. 3005-3008.

研究成果: Article

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