Environmentally friendly electroorganic synthesis using solid-supported acids and bases

Toshiki Tajima, Toshio Fuchigami

研究成果: Article査読

6 被引用数 (Scopus)

抄録

We have successfully developed novel electrolytic systems using solid-supported acids and bases. Anodic fluorination of various compounds using KF as a fluorine source and solid-supported acids as a supporting electrolyte was successfully carried out to provide the corresponding fluorinated products in good to excellent yields. On the other hand, anodic methoxylation, anodic acetoxylation, Kolbe electrolysis, and non-Kolbe electrolysis of various compounds using solid-supported bases as a precursor of supporting electrolytes were also conducted to afford the corresponding methoxylated, acetoxylated, Kolbe, and non-Kolbe products in moderate to excellent yields, respectively.

本文言語English
ページ(範囲)406-415
ページ数10
ジャーナルYuki Gosei Kagaku Kyokaishi/Journal of Synthetic Organic Chemistry
64
4
DOI
出版ステータスPublished - 2006 4
外部発表はい

ASJC Scopus subject areas

  • 有機化学

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