Formation of an intermediate compound with a B12H12 cluster: Experimental and theoretical studies on magnesium borohydride Mg(BH4)2

H. W. Li, K. Miwa, N. Ohba, T. Fujita, T. Sato, Y. Yan, S. Towata, M. W. Chen, S. Orimo

研究成果: Article査読

99 被引用数 (Scopus)

抄録

Experimental and theoretical studies on Mg(BH4)2 were carried out from the viewpoint of the formation of the intermediate compound MgB12H12 with B12H12 cluster. The full dehydriding and partial rehydriding reactions of Mg(BH4) 2 occurred according to the following multistep reaction: . The dehydriding reaction of Mg(BH4)2 starts at approximately 520 K, and 14.4 mass% of hydrogen is released upon heating to 800 K. Furthermore, 6.1 mass% of hydrogen can be rehydrided through the formation of MgB12H12. The mechanism for the formation of MgB 12H12 under the present rehydriding condition is also discussed.

本文言語English
論文番号204013
ジャーナルNanotechnology
20
20
DOI
出版ステータスPublished - 2009
外部発表はい

ASJC Scopus subject areas

  • バイオエンジニアリング
  • 化学 (全般)
  • 材料科学(全般)
  • 材料力学
  • 機械工学
  • 電子工学および電気工学

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「Formation of an intermediate compound with a B<sub>12</sub>H<sub>12</sub> cluster: Experimental and theoretical studies on magnesium borohydride Mg(BH<sub>4</sub>)<sub>2</sub>」の研究トピックを掘り下げます。これらがまとまってユニークなフィンガープリントを構成します。

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