Guest encapsulations in non-porous crystals of fully fluorinated dinuclear metal complexes with the M2O2 core (M = Fe3+, Co2+, Ni2+)

Ryu Gonda, Izabela Irena Rzeznicka, Yuki Kinoshita, Sayaka Uchida, Akiko Hori

研究成果: Article

1 引用 (Scopus)

抜粋

Two different coordination types of fully fluorinated dinuclear metal complexes, [Fe2L4(OMe)2] and [M2L4(OH2)2] (M = Co2+, Ni2+ and HL = bis(pentafluorobenzoyl)methane), were obtained. All of the complexes form non-porous crystals, which act as hosts for the adsorption of various benzene derivatives, e.g., benzene, toluene, p-xylene, anisole, and small gas molecules, e.g., CO2, O2, and NO. The complex of iron selectively adsorbs NO in high amounts and the complex of cobalt is found to store adsorbed O2.

元の言語English
ページ(範囲)9062-9066
ページ数5
ジャーナルDalton Transactions
48
発行部数25
DOI
出版物ステータスPublished - 2019 1 1

ASJC Scopus subject areas

  • Inorganic Chemistry

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