Hydrogen evolution from cathodically charged two-phase (Ti3Al + TiAl) titanium aluminides

Akito Takasaki, Yoshio Furuya, Kozo Ojima, Youji Taneda

研究成果: Article

16 引用 (Scopus)

抄録

Ti-45Al and Ti-50Al (at.%) titanium aluminides, whose microstructures consisted of Ti3Al (α2) and TiAl (γ), were cathodically hydrogen-charged in a 5% H2SO4 solution for charging times up to 14.4 ks (4 h), and the dissociation process of a hydride and the hydrogen evolution process during heating were investigated by thermal analyses (differential thermal analysis and thermal desorption spectroscopy). The hydride formed during cathodic charging dissociated at the temperature of about 700 K (427 °C), and corresponding to the hydride dissociation, hydrogen gas was evolved from the alloys at the dissociation temperature. In both alloys, accelerated hydrogen evolutions were observed at the lower temperatures than that for hydride dissociation. The evolution of hydrogen in the Ti-50Al alloy was extremely accelerated at about 523 K (250 °C) and the Ti-45Al at about 600 K (323 °C). The difference in the accelerated evolution temperatures was strongly dependent on the microstructures, in which structural imperfections, such as microvoids or internal cracks, could be formed during cathodic charging. The Ti-45Al alloy picked up about 1.5-times as much hydrogen as the Ti-50Al alloy, and more than 80% of the hydrogen was concentrated at the surface layer up to 20 μm in depth from the surface of the sample.

元の言語English
ページ(範囲)299-304
ページ数6
ジャーナルJournal of Alloys and Compounds
224
発行部数2
DOI
出版物ステータスPublished - 1995 7 1
外部発表Yes

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Titanium
Hydrogen
Hydrides
Thermal desorption spectroscopy
Temperature
Microstructure
Industrial heating
Differential thermal analysis
Gases
Cracks
Defects

ASJC Scopus subject areas

  • Mechanical Engineering
  • Mechanics of Materials
  • Materials Chemistry
  • Metals and Alloys

これを引用

Hydrogen evolution from cathodically charged two-phase (Ti3Al + TiAl) titanium aluminides. / Takasaki, Akito; Furuya, Yoshio; Ojima, Kozo; Taneda, Youji.

:: Journal of Alloys and Compounds, 巻 224, 番号 2, 01.07.1995, p. 299-304.

研究成果: Article

Takasaki, Akito ; Furuya, Yoshio ; Ojima, Kozo ; Taneda, Youji. / Hydrogen evolution from cathodically charged two-phase (Ti3Al + TiAl) titanium aluminides. :: Journal of Alloys and Compounds. 1995 ; 巻 224, 番号 2. pp. 299-304.
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abstract = "Ti-45Al and Ti-50Al (at.{\%}) titanium aluminides, whose microstructures consisted of Ti3Al (α2) and TiAl (γ), were cathodically hydrogen-charged in a 5{\%} H2SO4 solution for charging times up to 14.4 ks (4 h), and the dissociation process of a hydride and the hydrogen evolution process during heating were investigated by thermal analyses (differential thermal analysis and thermal desorption spectroscopy). The hydride formed during cathodic charging dissociated at the temperature of about 700 K (427 °C), and corresponding to the hydride dissociation, hydrogen gas was evolved from the alloys at the dissociation temperature. In both alloys, accelerated hydrogen evolutions were observed at the lower temperatures than that for hydride dissociation. The evolution of hydrogen in the Ti-50Al alloy was extremely accelerated at about 523 K (250 °C) and the Ti-45Al at about 600 K (323 °C). The difference in the accelerated evolution temperatures was strongly dependent on the microstructures, in which structural imperfections, such as microvoids or internal cracks, could be formed during cathodic charging. The Ti-45Al alloy picked up about 1.5-times as much hydrogen as the Ti-50Al alloy, and more than 80{\%} of the hydrogen was concentrated at the surface layer up to 20 μm in depth from the surface of the sample.",
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