Hydrogen storage by earth-abundant metals, synthesis and characterization of Al3FeH3.9

Hiroyuki Saitoh, Toyoto Sato, Mai Tanikami, Kazutaka Ikeda, Akihiko Machida, Tetsu Watanuki, Tomitsugu Taguchi, Shunya Yamamoto, Tetsuya Yamaki, Shigeyuki Takagi, Toshiya Otomo, Shin ichi Orimo

研究成果: Article査読

1 被引用数 (Scopus)

抄録

Among the various functionalities of hydrides, their use in hydrogen storage has been the most intensively studied because hydrides can store hydrogen compactly and safely. Thus, hydrides are key materials for the hydrogen economy. Here, the hydrogen storage material Al3FeH3.9 has been synthesized from cost-effective earth-abundant metals, Fe and Al. Hydrides consisting of Al and transition metals with low hydrogen affinities are rare because such alloys are unstable. However, it is expected that appropriate mixing of the chemical states of hydrogen atoms would allow synthesis of Al-Fe hydrides. The experimentally determined crystal structure of Al3FeD3.9 suggests realization of the mixing of the chemical state of hydrogen. Al3FeH3.9 is more thermodynamically stable than AlH3, and it is likely that the mixing of the chemical state of hydrogen atoms is the source of increased stability. The results of this study confirm that by controlling the chemical states of hydrogen, it is possible to tune the thermodynamic stability of hydrides and thus realize novel functional hydrides.

本文言語English
論文番号109953
ジャーナルMaterials and Design
208
DOI
出版ステータスPublished - 2021 10月
外部発表はい

ASJC Scopus subject areas

  • 材料科学(全般)
  • 材料力学
  • 機械工学

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