Imaging the hydrogenation of Mg thin films

Efi Hadjixenophontos, Manuel Roussel, Toyoto Sato, Andreas Weigel, Patrick Stender, Shin ichi Orimo, Guido Schmitz

研究成果: Article査読

11 被引用数 (Scopus)

抄録

Among the metal hydride materials, magnesium (Mg) and its alloys show excellent performance for hydrogen storage. The main drawback is the slow hydrogen absorption and desorption kinetics, the sole barrier to commercial adoption. In this work we use Mg thin films as model materials in order to study these kinetics, and observe the growth process of the hydride. Palladium (Pd) is used as a catalyst coating for improving the conditions of hydrogenation. The hydride formation is followed by in-situ X-ray diffraction. Microscopic imaging of the co-existence of Mg and MgH2 is presented. The microstructure change is clearly visible in the micrographs, despite the fact that sample preparation damages the hydride phase. The transformation from columnar grains of the as-deposited Mg thin film, to a grainy equi-axed structure film indicate that the hydride is observed. The hydride is immediately formed at the interface between the Pd and the Mg thin film and grows in a layer-like reaction towards the substrate (SiO2). These combined techniques provide an efficient methodology to follow the kinetics of hydride formation within the layer, and study further the diffusion coefficients and mechanism of hydrogenation.

本文言語English
ページ(範囲)22411-22416
ページ数6
ジャーナルInternational Journal of Hydrogen Energy
42
35
DOI
出版ステータスPublished - 2017 8 31
外部発表はい

ASJC Scopus subject areas

  • 再生可能エネルギー、持続可能性、環境
  • 燃料技術
  • 凝縮系物理学
  • エネルギー工学および電力技術

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