Indirect anodic oxidation based on the cation exchange reaction between alkaline (earth) metal halides and solid-supported acids

Atsushi Nakajima, Yuta Doi, Toshio Fuchigami, Toshiki Tajima

研究成果: Article

2 引用 (Scopus)

抜粋

We have developed a novel electrolytic system for indirect anodic oxidation based on the cation exchange reaction between alkaline (earth) metal halides and solid-supported acids. It was demonstrated that hydrogen halides derived from the cation exchange reaction act as not only a supporting electrolyte but also a mediator in acetonitrile. On the basis of the electrolytic system, indirect anodic oxidation of various benzyl alcohols in the presence of 2,6-lutidine was successfully achieved by controlled potential electrolysis to provide the corresponding benzaldehydes in good to excellent yields.

元の言語English
ページ(範囲)177-180
ページ数4
ジャーナルJournal of Electroanalytical Chemistry
623
発行部数2
DOI
出版物ステータスPublished - 2008 11 15
外部発表Yes

ASJC Scopus subject areas

  • Analytical Chemistry
  • Chemical Engineering(all)
  • Electrochemistry

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