Influence of trace lithium addition on the structure and properties of K0.5Na0.5NbO3-based single crystals

Dedong Li, Minhong Jiang, Shengnan Han, Qi Jin, Yaping Xu, Xiaoyu Yao, Kexiang Zhang, Lin Li, Lei Miao, Changrong Zhou, Guanghui Rao

研究成果: Article査読

抄録

K0.5Na0.5NbO3 single crystal with trace amounts of lithium addition was grown by the seed-free solid-state crystal growth method. The Li addition is helpful for the growth of the crystals and improves the properties of the K0.5Na0.5NbO3 single crystals. A small amounts (0.2–0.3 at.%) of Li addition can trigger the formation of around 25% tetragonal phase. The occurrence of the phase transition may be due to the variety of the K/Na atomic ratio after Li substitution in both the Na and K sites. The optimum amount of Li addition in the crystal is 0.2–0.3 at.% in order to obtain a well performance K0.5Na0.5NbO3-based single crystal. The best electrical performance of these K0.5Na0.5NbO3-based crystals can be achieved as follows: d33 = 255 pC/N, tanδ = 1%, d* 33 = 313 pm/V, and Pr = 26.1 μC/cm2, indicating that the structure and properties of K0.5Na0.5NbO3-based crystals grown by the seed-free solid-state crystal growth method can be closely affected by trace lithium carbonate addition.

本文言語English
ページ(範囲)4857-4866
ページ数10
ジャーナルJournal of Materials Science: Materials in Electronics
31
6
DOI
出版ステータスPublished - 2020 3 1
外部発表はい

ASJC Scopus subject areas

  • 電子材料、光学材料、および磁性材料
  • 原子分子物理学および光学
  • 凝縮系物理学
  • 電子工学および電気工学

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「Influence of trace lithium addition on the structure and properties of K<sub>0.5</sub>Na<sub>0.5</sub>NbO<sub>3</sub>-based single crystals」の研究トピックを掘り下げます。これらがまとまってユニークなフィンガープリントを構成します。

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