Inorganic nanocomposite films with polymer nanofillers made by the concurrent multi-beam multi-target pulsed laser deposition

Abdalla M. Darwish, Sergey S. Sarkisov, Paolo Mele, Shrikant Saini, Shaelynn Moore, Tyler Bastian, Wydglif Dorlus, Xiaodong Zhang, Brent Koplitz

研究成果: Conference contribution

抄録

We report on the new class of inorganic nanocomposite films with the inorganic phase hosting the polymer nanofillers made by the concurrent multi-beam multi-target pulsed laser deposition of the inorganic target material and matrix assisted pulsed laser evaporation of the polymer (MBMT-PLD/MAPLE). We used the exemplary nanocomposite thermoelectric films of aluminum-doped ZnO known as AZO with the nanofillers made of poly(methyl methacrylate) known as PMMA on various substrates such as SrTiO3, sapphire, fused silica, and polyimide. The AZO target was ablated with the second harmonic (532 nm) of the Nd:YAG Q-switched laser while PMMA was evaporated from its solution in chlorobenzene frozen in liquid nitrogen with the fundamental harmonic (1064 nm) of the same laser (50 Hz pulse repetition rate). The introduction of the polymer nanofillers increased the electrical conductivity of the nanocomposite films (possibly due to the carbonization of PMMA and the creation of additional channels of electric current) three times and reduced the thermal conductivity by 1.25 times as compared to the pure AZO films. Accordingly, the increase of the thermoelectric figure-of merit ZT would be ∼ 4 times. The best performance was observed for the sapphire substrates where the films were the most uniform. The results point to a huge potential of the optimization of a broad variety of optical, opto-electronic, and solar-power nanocomposite inorganic films by the controllable introduction of the polymer nanofillers using the MBMT-PLD/MAPLE method.

元の言語English
ホスト出版物のタイトルPhotonic Fiber and Crystal Devices
ホスト出版物のサブタイトルAdvances in Materials and Innovations in Device Applications XI
編集者Shizhuo Yin, Ruyan Guo
出版者SPIE
10382
ISBN(電子版)9781510612211
DOI
出版物ステータスPublished - 2017 1 1
外部発表Yes
イベントPhotonic Fiber and Crystal Devices: Advances in Materials and Innovations in Device Applications XI 2017 - San Diego, United States
継続期間: 2017 8 62017 8 7

Other

OtherPhotonic Fiber and Crystal Devices: Advances in Materials and Innovations in Device Applications XI 2017
United States
San Diego
期間17/8/617/8/7

Fingerprint

Nanocomposite films
Pulsed laser deposition
pulsed laser deposition
Polymethyl Methacrylate
nanocomposites
Polymers
polymers
Aluminum Oxide
Pulsed lasers
Sapphire
Nanocomposites
Evaporation
pulsed lasers
sapphire
Q switched lasers
Pulse repetition rate
evaporation
Carbonization
harmonics
Electric currents

ASJC Scopus subject areas

  • Electronic, Optical and Magnetic Materials
  • Condensed Matter Physics
  • Computer Science Applications
  • Applied Mathematics
  • Electrical and Electronic Engineering

これを引用

Darwish, A. M., Sarkisov, S. S., Mele, P., Saini, S., Moore, S., Bastian, T., ... Koplitz, B. (2017). Inorganic nanocomposite films with polymer nanofillers made by the concurrent multi-beam multi-target pulsed laser deposition. : S. Yin, & R. Guo (版), Photonic Fiber and Crystal Devices: Advances in Materials and Innovations in Device Applications XI (巻 10382). [1038202] SPIE. https://doi.org/10.1117/12.2273400

Inorganic nanocomposite films with polymer nanofillers made by the concurrent multi-beam multi-target pulsed laser deposition. / Darwish, Abdalla M.; Sarkisov, Sergey S.; Mele, Paolo; Saini, Shrikant; Moore, Shaelynn; Bastian, Tyler; Dorlus, Wydglif; Zhang, Xiaodong; Koplitz, Brent.

Photonic Fiber and Crystal Devices: Advances in Materials and Innovations in Device Applications XI. 版 / Shizhuo Yin; Ruyan Guo. 巻 10382 SPIE, 2017. 1038202.

研究成果: Conference contribution

Darwish, AM, Sarkisov, SS, Mele, P, Saini, S, Moore, S, Bastian, T, Dorlus, W, Zhang, X & Koplitz, B 2017, Inorganic nanocomposite films with polymer nanofillers made by the concurrent multi-beam multi-target pulsed laser deposition. : S Yin & R Guo (版), Photonic Fiber and Crystal Devices: Advances in Materials and Innovations in Device Applications XI. 巻. 10382, 1038202, SPIE, Photonic Fiber and Crystal Devices: Advances in Materials and Innovations in Device Applications XI 2017, San Diego, United States, 17/8/6. https://doi.org/10.1117/12.2273400
Darwish AM, Sarkisov SS, Mele P, Saini S, Moore S, Bastian T その他. Inorganic nanocomposite films with polymer nanofillers made by the concurrent multi-beam multi-target pulsed laser deposition. : Yin S, Guo R, 編集者, Photonic Fiber and Crystal Devices: Advances in Materials and Innovations in Device Applications XI. 巻 10382. SPIE. 2017. 1038202 https://doi.org/10.1117/12.2273400
Darwish, Abdalla M. ; Sarkisov, Sergey S. ; Mele, Paolo ; Saini, Shrikant ; Moore, Shaelynn ; Bastian, Tyler ; Dorlus, Wydglif ; Zhang, Xiaodong ; Koplitz, Brent. / Inorganic nanocomposite films with polymer nanofillers made by the concurrent multi-beam multi-target pulsed laser deposition. Photonic Fiber and Crystal Devices: Advances in Materials and Innovations in Device Applications XI. 編集者 / Shizhuo Yin ; Ruyan Guo. 巻 10382 SPIE, 2017.
@inproceedings{8ac0ba150b6448b684a82cd23893e41b,
title = "Inorganic nanocomposite films with polymer nanofillers made by the concurrent multi-beam multi-target pulsed laser deposition",
abstract = "We report on the new class of inorganic nanocomposite films with the inorganic phase hosting the polymer nanofillers made by the concurrent multi-beam multi-target pulsed laser deposition of the inorganic target material and matrix assisted pulsed laser evaporation of the polymer (MBMT-PLD/MAPLE). We used the exemplary nanocomposite thermoelectric films of aluminum-doped ZnO known as AZO with the nanofillers made of poly(methyl methacrylate) known as PMMA on various substrates such as SrTiO3, sapphire, fused silica, and polyimide. The AZO target was ablated with the second harmonic (532 nm) of the Nd:YAG Q-switched laser while PMMA was evaporated from its solution in chlorobenzene frozen in liquid nitrogen with the fundamental harmonic (1064 nm) of the same laser (50 Hz pulse repetition rate). The introduction of the polymer nanofillers increased the electrical conductivity of the nanocomposite films (possibly due to the carbonization of PMMA and the creation of additional channels of electric current) three times and reduced the thermal conductivity by 1.25 times as compared to the pure AZO films. Accordingly, the increase of the thermoelectric figure-of merit ZT would be ∼ 4 times. The best performance was observed for the sapphire substrates where the films were the most uniform. The results point to a huge potential of the optimization of a broad variety of optical, opto-electronic, and solar-power nanocomposite inorganic films by the controllable introduction of the polymer nanofillers using the MBMT-PLD/MAPLE method.",
keywords = "matrix assisted pulsed laser evaporation, multi-beam pulsed laser deposition, Nanocomposites, polymer nanofillers, pulsed laser deposition, thermoelectric energy harvesters, thermoelectric films",
author = "Darwish, {Abdalla M.} and Sarkisov, {Sergey S.} and Paolo Mele and Shrikant Saini and Shaelynn Moore and Tyler Bastian and Wydglif Dorlus and Xiaodong Zhang and Brent Koplitz",
year = "2017",
month = "1",
day = "1",
doi = "10.1117/12.2273400",
language = "English",
volume = "10382",
editor = "Shizhuo Yin and Ruyan Guo",
booktitle = "Photonic Fiber and Crystal Devices",
publisher = "SPIE",

}

TY - GEN

T1 - Inorganic nanocomposite films with polymer nanofillers made by the concurrent multi-beam multi-target pulsed laser deposition

AU - Darwish, Abdalla M.

AU - Sarkisov, Sergey S.

AU - Mele, Paolo

AU - Saini, Shrikant

AU - Moore, Shaelynn

AU - Bastian, Tyler

AU - Dorlus, Wydglif

AU - Zhang, Xiaodong

AU - Koplitz, Brent

PY - 2017/1/1

Y1 - 2017/1/1

N2 - We report on the new class of inorganic nanocomposite films with the inorganic phase hosting the polymer nanofillers made by the concurrent multi-beam multi-target pulsed laser deposition of the inorganic target material and matrix assisted pulsed laser evaporation of the polymer (MBMT-PLD/MAPLE). We used the exemplary nanocomposite thermoelectric films of aluminum-doped ZnO known as AZO with the nanofillers made of poly(methyl methacrylate) known as PMMA on various substrates such as SrTiO3, sapphire, fused silica, and polyimide. The AZO target was ablated with the second harmonic (532 nm) of the Nd:YAG Q-switched laser while PMMA was evaporated from its solution in chlorobenzene frozen in liquid nitrogen with the fundamental harmonic (1064 nm) of the same laser (50 Hz pulse repetition rate). The introduction of the polymer nanofillers increased the electrical conductivity of the nanocomposite films (possibly due to the carbonization of PMMA and the creation of additional channels of electric current) three times and reduced the thermal conductivity by 1.25 times as compared to the pure AZO films. Accordingly, the increase of the thermoelectric figure-of merit ZT would be ∼ 4 times. The best performance was observed for the sapphire substrates where the films were the most uniform. The results point to a huge potential of the optimization of a broad variety of optical, opto-electronic, and solar-power nanocomposite inorganic films by the controllable introduction of the polymer nanofillers using the MBMT-PLD/MAPLE method.

AB - We report on the new class of inorganic nanocomposite films with the inorganic phase hosting the polymer nanofillers made by the concurrent multi-beam multi-target pulsed laser deposition of the inorganic target material and matrix assisted pulsed laser evaporation of the polymer (MBMT-PLD/MAPLE). We used the exemplary nanocomposite thermoelectric films of aluminum-doped ZnO known as AZO with the nanofillers made of poly(methyl methacrylate) known as PMMA on various substrates such as SrTiO3, sapphire, fused silica, and polyimide. The AZO target was ablated with the second harmonic (532 nm) of the Nd:YAG Q-switched laser while PMMA was evaporated from its solution in chlorobenzene frozen in liquid nitrogen with the fundamental harmonic (1064 nm) of the same laser (50 Hz pulse repetition rate). The introduction of the polymer nanofillers increased the electrical conductivity of the nanocomposite films (possibly due to the carbonization of PMMA and the creation of additional channels of electric current) three times and reduced the thermal conductivity by 1.25 times as compared to the pure AZO films. Accordingly, the increase of the thermoelectric figure-of merit ZT would be ∼ 4 times. The best performance was observed for the sapphire substrates where the films were the most uniform. The results point to a huge potential of the optimization of a broad variety of optical, opto-electronic, and solar-power nanocomposite inorganic films by the controllable introduction of the polymer nanofillers using the MBMT-PLD/MAPLE method.

KW - matrix assisted pulsed laser evaporation

KW - multi-beam pulsed laser deposition

KW - Nanocomposites

KW - polymer nanofillers

KW - pulsed laser deposition

KW - thermoelectric energy harvesters

KW - thermoelectric films

UR - http://www.scopus.com/inward/record.url?scp=85034019380&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=85034019380&partnerID=8YFLogxK

U2 - 10.1117/12.2273400

DO - 10.1117/12.2273400

M3 - Conference contribution

AN - SCOPUS:85034019380

VL - 10382

BT - Photonic Fiber and Crystal Devices

A2 - Yin, Shizhuo

A2 - Guo, Ruyan

PB - SPIE

ER -