Inter-molecular π-stacking and F⋯F inter-actions of fluorine-substituted meso-alkynylporphyrin

Yuta Marushima, Yuri Uchiumi, Kenichi Ogu, Akiko Hori

研究成果: Article査読

8 被引用数 (Scopus)

抄録

Two C2-symmetric meso-alkynylporphyrins, namely 5,15-bis-[(4-butyl-2,3,5,6- tetra-fluoro-phen-yl)ethyn-yl]-10,20-dipropyl-porphyrin, C50H 42F8N4, (I), and 5,15-bis-[(4-butyl-phen-yl) ethyn-yl]-10,20-dipropyl-porphyrin, C50H50N4, (II), show remarkable π-π stacking that forms columns of porphyrin centers. The tetra-fluoro-phenyl-ene moieties in (I) show inter-molecular inter-actions with each other through the F atoms, forming one-dimensional ribbons. No significant π-π inter-actions are observed in the plane of the phenyl-ene and tetra-fluoro-phenyl-ene moieties in either (I) or (II). The molecules of both compounds lie about inversion centers.

本文言語English
ページ(範囲)o406-o409
ジャーナルActa Crystallographica Section C: Crystal Structure Communications
66
8
DOI
出版ステータスPublished - 2010 8 15
外部発表はい

ASJC Scopus subject areas

  • 生化学、遺伝学、分子生物学(全般)

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