Intramolecular carbostannation reaction of active methine compounds with an unactivated C-C π-bond mediated by SnCl4-Et3N

O. Kitagawa; H. Fujiwara; T. Suzuki; T. Taguchi; M. Shiro

doi:10.1021/jo000784z

Intramolecular carbostannation reaction of active methine compounds with an unactivated C-C π-bond mediated by SnCl₄-Et₃N

O. Kitagawa, H. Fujiwara, T. Suzuki, T. Taguchi, M. Shiro

研究成果: Article › 査読

41 被引用数 (Scopus)

抄録

In the presence of SnCl₄ and Et₃N, intramolecular carbostannation reaction of various active methine compounds having an 'unactivated alkenyl, alkynyl, or allenyl group proceeds in good yields with complete regioselectivity. The subsequent reaction of the resulting Sn intermediates with some electrophiles provides functionalized cyclopentane and cyclohexane derivatives.

本文言語	English
ページ（範囲）	6819-6825
ページ数	7
ジャーナル	Journal of Organic Chemistry
巻	65
号	21
DOI	https://doi.org/10.1021/jo000784z
出版ステータス	Published - 2000 10 20
外部発表	はい

ASJC Scopus subject areas

有機化学

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10.1021/jo000784z

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「Intramolecular carbostannation reaction of active methine compounds with an unactivated C-C π-bond mediated by SnCl<sub>4</sub>-Et<sub>3</sub>N」の研究トピックを掘り下げます。これらがまとまってユニークなフィンガープリントを構成します。

引用スタイル

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AU - Taguchi, T.

AU - Shiro, M.

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AB - In the presence of SnCl4 and Et3N, intramolecular carbostannation reaction of various active methine compounds having an 'unactivated alkenyl, alkynyl, or allenyl group proceeds in good yields with complete regioselectivity. The subsequent reaction of the resulting Sn intermediates with some electrophiles provides functionalized cyclopentane and cyclohexane derivatives.

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