High-pressure synthesis, crystal structure, and physical properties of mercury-containing transition-metal oxides were introduced from a viewpoint of coordination chemistry of mercury. It is interesting that mercury behaves not only as a cation (Hg2＋) but also as a molecule anion (HgO2 2－) and metal cluster (Hgn). Since mercury is volatile, high-pressure synthesis is an essential technique to produce new mercury-containing compounds.
|ジャーナル||Review of High Pressure Science and Technology/Koatsuryoku No Kagaku To Gijutsu|
|出版ステータス||Published - 2014 9月 18|
ASJC Scopus subject areas
- 化学 (全般)