Mercury-containing transition-metal oxides: Its high-pressure synthesis and variety of Hg compounds

研究成果: Review article

抄録

High-pressure synthesis, crystal structure, and physical properties of mercury-containing transition-metal oxides were introduced from a viewpoint of coordination chemistry of mercury. It is interesting that mercury behaves not only as a cation (Hg2+) but also as a molecule anion (HgO2 2-) and metal cluster (Hgn). Since mercury is volatile, high-pressure synthesis is an essential technique to produce new mercury-containing compounds.

元の言語English
ページ(範囲)188-194
ページ数7
ジャーナルReview of High Pressure Science and Technology/Koatsuryoku No Kagaku To Gijutsu
24
発行部数3
DOI
出版物ステータスPublished - 2014 9 18
外部発表Yes

Fingerprint

Mercury (metal)
Mercury
Oxides
Transition metals
metal oxides
transition metals
synthesis
Negative ions
Physical properties
Crystal structure
Positive ions
mercury compounds
Molecules
metal clusters
Metals
physical properties
Anions
chemistry
Cations
anions

ASJC Scopus subject areas

  • Condensed Matter Physics
  • Materials Science(all)
  • Chemistry(all)

これを引用

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abstract = "High-pressure synthesis, crystal structure, and physical properties of mercury-containing transition-metal oxides were introduced from a viewpoint of coordination chemistry of mercury. It is interesting that mercury behaves not only as a cation (Hg2+) but also as a molecule anion (HgO2 2-) and metal cluster (Hgn). Since mercury is volatile, high-pressure synthesis is an essential technique to produce new mercury-containing compounds.",
keywords = "Cubic anvil press, High-pressure synthesis, Mercury, Metal-insulator transition, Superconductivity, Transition-metal oxides",
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KW - Metal-insulator transition

KW - Superconductivity

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