Metallization of La1/3NbO3 by lithium incorporation

Ayako Yamamoto, H. Uchiyama, S. Tajima

研究成果: Article

6 引用 (Scopus)

抄録

Lithium ion was successfully introduced into La1/3NbO 3 with an A-site-deficient perovskite-type structure. The crystal structure and transport properties of La1/3LixNbO 3 were investigated as a function of Li content (x = 0-0.59). The lattice parameters of La1/3LixNbO3 with an orthorhombic cell were enlarged with increasing Li content for x ≤ 0.3, and the structure was transformed to a pseudo-tetragonal cell for x = 0.44. The temperature dependence of electrical resistivity gradually changed from insulating to metallic with increasing x, and thermoelectric power measurement indicated that the carriers were electrons. In X-ray photoelectron spectra of the incorporated samples, Nb3d 4+ peaks appeared in addition to Nb3d 5+ peaks, which was consistent with the change of the transport properties. In spite of the success of metallization, no diamagnetic signal indicative of supercondcutivity was observed in La 1/3Li0.59NbO3 down to 1.8K.

元の言語English
ページ(範囲)1691-1699
ページ数9
ジャーナルMaterials Research Bulletin
39
発行部数11
DOI
出版物ステータスPublished - 2004 9 1
外部発表Yes

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Metallizing
Lithium
Transport properties
lithium
transport properties
Thermoelectric power
Photoelectrons
cells
Perovskite
Lattice constants
lattice parameters
photoelectrons
Crystal structure
Ions
X rays
temperature dependence
electrical resistivity
crystal structure
Electrons
ions

ASJC Scopus subject areas

  • Materials Science(all)
  • Condensed Matter Physics
  • Mechanics of Materials
  • Mechanical Engineering

これを引用

Metallization of La1/3NbO3 by lithium incorporation. / Yamamoto, Ayako; Uchiyama, H.; Tajima, S.

:: Materials Research Bulletin, 巻 39, 番号 11, 01.09.2004, p. 1691-1699.

研究成果: Article

Yamamoto, Ayako ; Uchiyama, H. ; Tajima, S. / Metallization of La1/3NbO3 by lithium incorporation. :: Materials Research Bulletin. 2004 ; 巻 39, 番号 11. pp. 1691-1699.
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N2 - Lithium ion was successfully introduced into La1/3NbO 3 with an A-site-deficient perovskite-type structure. The crystal structure and transport properties of La1/3LixNbO 3 were investigated as a function of Li content (x = 0-0.59). The lattice parameters of La1/3LixNbO3 with an orthorhombic cell were enlarged with increasing Li content for x ≤ 0.3, and the structure was transformed to a pseudo-tetragonal cell for x = 0.44. The temperature dependence of electrical resistivity gradually changed from insulating to metallic with increasing x, and thermoelectric power measurement indicated that the carriers were electrons. In X-ray photoelectron spectra of the incorporated samples, Nb3d 4+ peaks appeared in addition to Nb3d 5+ peaks, which was consistent with the change of the transport properties. In spite of the success of metallization, no diamagnetic signal indicative of supercondcutivity was observed in La 1/3Li0.59NbO3 down to 1.8K.

AB - Lithium ion was successfully introduced into La1/3NbO 3 with an A-site-deficient perovskite-type structure. The crystal structure and transport properties of La1/3LixNbO 3 were investigated as a function of Li content (x = 0-0.59). The lattice parameters of La1/3LixNbO3 with an orthorhombic cell were enlarged with increasing Li content for x ≤ 0.3, and the structure was transformed to a pseudo-tetragonal cell for x = 0.44. The temperature dependence of electrical resistivity gradually changed from insulating to metallic with increasing x, and thermoelectric power measurement indicated that the carriers were electrons. In X-ray photoelectron spectra of the incorporated samples, Nb3d 4+ peaks appeared in addition to Nb3d 5+ peaks, which was consistent with the change of the transport properties. In spite of the success of metallization, no diamagnetic signal indicative of supercondcutivity was observed in La 1/3Li0.59NbO3 down to 1.8K.

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