Molecular orientation of oligothiophene-based polyamide thin films fabricated by vapor deposition polymerization

Hitoshi Muguruma, Kazutoshi Matsumura, Shu Hotta

研究成果: Article査読

5 被引用数 (Scopus)

抄録

We report the orientated polyamide thin films having oligothiophene segments in the main chain by a vapor deposition polymerization technique. The films were prepared by the condensation reaction between 2,2′-bithiophene-5,5′-dicarbonyl dichloride and α,ω-bis(aminomethyl)oligothiophene whose degree of polymerization are trimer and tetramer. X-Ray diffraction measurements indicate that the morphology of the films shows a regular crystalline structure and the molecular axis is oblique against the substrate plane. The molecular orientation of the films strongly depends on the ratio of the vapor fluxes of the two reactants to be deposited.

本文言語English
ページ(範囲)77-80
ページ数4
ジャーナルThin Solid Films
405
1-2
DOI
出版ステータスPublished - 2002 2 22

ASJC Scopus subject areas

  • 電子材料、光学材料、および磁性材料
  • 表面および界面
  • 表面、皮膜および薄膜
  • 金属および合金
  • 材料化学

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