Notable structural property of 2,4,6-Tri- tert -butylanilide enolates: Interconversion between the rotamers and their reactivity

Yusuke Ohnishi, Masahi Sakai, Shouta Nakao, Osamu Kitagawa

研究成果: Article

8 引用 (Scopus)

抜粋

Interconversion between the separable 2,4,6-tri-tert-butylanilide rotamers was found to easily occur through formation of the lithium enolate. Protonation of the anilide enolate gave the anilide rotamer mixture of E-major. On the other hand, reactions of lithium enolate prepared from 2,4,6-tri-tert- butylpropionanilide with alkyl bromides preferentially afforded a Z-rotamer of alkylated products.

元の言語English
ページ(範囲)2840-2843
ページ数4
ジャーナルOrganic Letters
13
発行部数11
DOI
出版物ステータスPublished - 2011 6 3

    フィンガープリント

ASJC Scopus subject areas

  • Organic Chemistry
  • Physical and Theoretical Chemistry
  • Biochemistry

これを引用