抄録
New axially chiral N-acryl-N-allyl-o-tert-butylanilide and N-(o-tert-butylphenyl)-2-methylmaleimide with high optical purity and definite absolute configurations were prepared from o-tert-butylaniline and (S)-O-acetyl lactic acid or (R)-2-methylsuccinic acid, respectively. Iodine- or Lewis acid-mediated asymmetric Diels-Alder reaction of these axially chiral compounds with various dienes proceeded with high endo and diastereofacial selectivity.
本文言語 | English |
---|---|
ページ(範囲) | 2634-2640 |
ページ数 | 7 |
ジャーナル | Journal of Organic Chemistry |
巻 | 63 |
号 | 8 |
DOI | |
出版ステータス | Published - 1998 4月 17 |
外部発表 | はい |
ASJC Scopus subject areas
- 有機化学