Oxygen storage properties and catalytic activity of layer-ordered perovskites BaY1 - XGdxMn2O5 + δ

Alicja Klimkowicz, K. Świerczek, T. Rzasa, Akito Takasaki, B. Dabrowski

研究成果: Article

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Crystal structure, oxygen storage-related and preliminary anaerobic methane combustion studies were conducted for BaY1 - xGdxMn2O5 + δ (0, 0.25, 0.5, 0.75 and 1) series of oxides prepared by a sol-gel method. All samples were found to possess layered-type A-site cation ordering, with the unit cell volume linearly dependent on the average radius of Y1 - xGdx for both the reduced and the oxidized materials. The oxygen content in the temperature range of 400°C-600°C indicates change on the order of 1 atomic mole, occurring when the sample's surrounding atmosphere was changed from air to 5 vol.% H2 in Ar. The time dependence of the reduction shows activated character on temperature, with an activation energy, which seems to be related to the oxygen diffusion in the bulk of the materials. Initial data concerning methane combustion in oxygen-free conditions show promising catalytic activity of BaYMn2O6 at elevated temperatures.

元の言語English
ページ(範囲)43-47
ページ数5
ジャーナルSolid State Ionics
288
DOI
出版物ステータスPublished - 2016 5 1

ASJC Scopus subject areas

  • Materials Science(all)
  • Condensed Matter Physics
  • Chemistry(all)

フィンガープリント Oxygen storage properties and catalytic activity of layer-ordered perovskites BaY<sub>1</sub> <sub>- X</sub>Gd<sub>x</sub>Mn<sub>2</sub>O<sub>5</sub> <sub>+</sub> <sub>δ</sub>' の研究トピックを掘り下げます。これらはともに一意のフィンガープリントを構成します。

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