Oxygen storage-related properties of substituted BaLnMn <inf>2</inf> O <inf>5</inf>+δ A-site ordered manganites

Konrad Swierczek, Alicja Klimkowicz, Anna Niemczyk, Anna Olszewska, Tomasz Rząsa, Janina Molenda, Akito Takasaki

研究成果: Article

7 引用 (Scopus)

抄録

In this work, we present results showing modification of the oxygen storage-related properties of perovskite-type oxides based on BaYMn<inf>2</inf>O<inf>5+</inf>δ, having A-site layer-type cation order. Y<sup>3+</sup> is the lightest among suitable cations, which allows to obtain such the structural order, and at the same time, it provides the highest theoretical oxygen storage capacity. However, substitution of Y<sup>3+</sup> by Sm<sup>3+</sup>cations may be beneficial, and BaY<inf>0.5</inf>Sm<inf>0.5</inf>Mn<inf>2</inf><inf>O</inf>5+δ material shows enhanced reduction kinetics. Furthermore, partial substitution of Ba<sup>2+ by Sr</sup>2+ increases reversible oxygen storage capacity, but at the same time slows down the reduction speed. In addition, for higher concentration of strontium, it is not possible to obtain single phase materials.

元の言語English
記事番号1440004
ジャーナルFunctional Materials Letters
7
発行部数6
DOI
出版物ステータスPublished - 2014 12 16

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Manganites
Cations
Positive ions
Oxygen
Substitution reactions
Strontium
Perovskite
Oxides
Kinetics

ASJC Scopus subject areas

  • Materials Science(all)

これを引用

Oxygen storage-related properties of substituted BaLnMn <inf>2</inf> O <inf>5</inf>+δ A-site ordered manganites. / Swierczek, Konrad; Klimkowicz, Alicja; Niemczyk, Anna; Olszewska, Anna; Rząsa, Tomasz; Molenda, Janina; Takasaki, Akito.

:: Functional Materials Letters, 巻 7, 番号 6, 1440004, 16.12.2014.

研究成果: Article

Swierczek, Konrad ; Klimkowicz, Alicja ; Niemczyk, Anna ; Olszewska, Anna ; Rząsa, Tomasz ; Molenda, Janina ; Takasaki, Akito. / Oxygen storage-related properties of substituted BaLnMn <inf>2</inf> O <inf>5</inf>+δ A-site ordered manganites. :: Functional Materials Letters. 2014 ; 巻 7, 番号 6.
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AU - Swierczek, Konrad

AU - Klimkowicz, Alicja

AU - Niemczyk, Anna

AU - Olszewska, Anna

AU - Rząsa, Tomasz

AU - Molenda, Janina

AU - Takasaki, Akito

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N2 - In this work, we present results showing modification of the oxygen storage-related properties of perovskite-type oxides based on BaYMn2O5+δ, having A-site layer-type cation order. Y3+ is the lightest among suitable cations, which allows to obtain such the structural order, and at the same time, it provides the highest theoretical oxygen storage capacity. However, substitution of Y3+ by Sm3+cations may be beneficial, and BaY0.5Sm0.5Mn2O5+δ material shows enhanced reduction kinetics. Furthermore, partial substitution of Ba2+ by Sr2+ increases reversible oxygen storage capacity, but at the same time slows down the reduction speed. In addition, for higher concentration of strontium, it is not possible to obtain single phase materials.

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