Peculiar nonlinear elasticity of polyrotaxane gels with movable cross-links revealed by multiaxial stretching

Yohsuke Bitoh, Norio Akuzawa, Kenji Urayama, Toshikazu Takigawa, Masatoshi Kidowaki, Kohzo Ito

研究成果: Article

41 引用 (Scopus)

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A peculiar rubber elasticity feature of polyrotaxane (PR) gels with cross-links capable of moving along network strands is revealed by general biaxial strain testing that varies the strains in the two orthogonal directions. The influence of the strain in one direction on the stress in the other direction in the PR gels with sufficiently low cross-link concentrations is much smaller than that in conventional elastomers and gels with fixed cross-links. The stress-strain behavior of the PR gels under various types of deformation is exceptionally close to the prediction of the neo-Hookean model with no explicit strain-coupling between the different principal directions other than that resulting from volume conservation. The minimal strain-coupling between different two directions is a pronounced feature for PR gels with movable cross-links to vary the network topology in response to imposed deformation.

元の言語English
ページ(範囲)8661-8667
ページ数7
ジャーナルMacromolecules
44
発行部数21
DOI
出版物ステータスPublished - 2011 11 8

ASJC Scopus subject areas

  • Organic Chemistry
  • Polymers and Plastics
  • Inorganic Chemistry
  • Materials Chemistry

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