Photo racemization of 2,2′-dihydroxy-1,1′-binaphthyl derivatives

Qingyu Wang, Adriana Pietropaolo, Mariagrazia Fortino, Zhiyi Song, Masayoshi Bando, Naofumi Naga, Tamaki Nakano

研究成果: Article査読

1 被引用数 (Scopus)

抄録

Photo racemization of 2,2′-dihydroxy-1,1′-binaphthyl (BINOL) and its monomethyl ether, monobutyl ether, and dimethyl ether was studied by means of circularly dichroism spectra, chiral HPLC, and theoretical calculations of rotation energy barriers. Racemization was fastest for BINOL and about one seventh as fast for the monomethyl and monobutyl ethers while it was too slow to be detected for the dimethyl ether under the present conditions.

本文言語English
ページ(範囲)317-324
ページ数8
ジャーナルChirality
34
2
DOI
出版ステータスPublished - 2022 2月

ASJC Scopus subject areas

  • 分析化学
  • 触媒
  • 薬理学
  • 創薬
  • 分光学
  • 有機化学

フィンガープリント

「Photo racemization of 2,2′-dihydroxy-1,1′-binaphthyl derivatives」の研究トピックを掘り下げます。これらがまとまってユニークなフィンガープリントを構成します。

引用スタイル