Picosecond time-resolved fluorescence spectroscopy of (Z)-1-(2-anthryl)-2-phenylethene and its model compounds: Understanding the photochemistry by distinguishing between the s-cis and s-trans rotamers

Takashi Karatsu, Hajime Itoh, Atsuko Nishigaki, Keijiro Fukui, Akihide Kitamura, Shigeki Matsuo, Hiroaki Misawa

研究成果: Article

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The photochemical reactions (Z-E isomerization and photocyclization) of the s-cis and s-trans rotamers of (Z)-1-(2-anthryl)-2-phenylethene (Z2APE) were investigated. The absorption, steady-state and picosecond time-resolved fluorescences, and transient absorption spectra were measured in order to achieve a better understanding of the rotamer photochemistry. The spectra were compared with those of the model compounds ((Z)-1-[2-(1-methylanthryl)]-2-phenylethene: Z1Me2APE and (Z)-1-[2-(3-methylanthryl)]-2-phenylethene: Z3Me2APE). It is confirmed that the s-trans rotamer undergoes only Z→E adiabatic isomerization and that the s-cis rotamer mainly photocyclizes to give the dihydrophenanthrene-type intermediate with a much faster rate constant (kcyc = 2.3 × 1010 s-1). The reason Z2APE does not give an aromatized photocyclization product (1,2-naphtho[a]anthracene, NA) is that the return of the dihydrophenanthrene-type intermediate to the Z isomer is much faster than the oxidation to produce NA.

元の言語English
ページ(範囲)6993-7001
ページ数9
ジャーナルJournal of Physical Chemistry A
104
発行部数30
DOI
出版物ステータスPublished - 2000 8 3
外部発表Yes

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry

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