Polypyrrole/Polymer Electrolyte Composites Prepared by in Situ Electropolymerization of Pyrrole as Cathode/Electrolyte Material for Facile Electron Transfer at the Solid Interface

Jin Amanokura, Yusuke Suzuki, Shin Ichiro Imabayashi, Masayoshi Watanabe

研究成果: Article査読

25 被引用数 (Scopus)

抄録

Polypyrrole (PPy)/ion-conducting polymer electrolyte (PE) composites are prepared by in situ electropolymerization of pyrrole in a solvent-free PE matrix which is formed by photocross-linking of triacrylated poly(ethylene oxide-co-propylene oxide) (TA). X-ray photoelectron spectroscopy measuremenls reveal the gradient structure at the PPy/PE interface where PPy is formed with the concentration gradient. For the composite film, a facile electron transfer across the PPy/PE interlace is demonstrated by a cyclic voltammogram for the doping-undoping process, and a decrease in the charge-transfer resistance at the interface is proved by an electrochemical impedance analysis. This is in marked contrast to a combined bilayer film of PPy and TA-based PE for which an electron transfer across the interface between two polymer films is not clearly observed. The composite exhibits charge-discharge performance, which suggests a possibility of fabricating solid-state batteries composed of conductive polymer electrode/ion-conductive PE/Li by one-step electrolysis.

本文言語English
ページ(範囲)D43-D48
ジャーナルJournal of the Electrochemical Society
148
4
DOI
出版ステータスPublished - 2001 4 1
外部発表はい

ASJC Scopus subject areas

  • 電子材料、光学材料、および磁性材料
  • 再生可能エネルギー、持続可能性、環境
  • 表面、皮膜および薄膜
  • 電気化学
  • 材料化学

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