Pressure effects on the twisted intramolecular charge transfer (TICT) phenomenon

Ryuichi Hayashi, Shigeo Tazuke, Curtis W. Frank

研究成果: Article査読

34 被引用数 (Scopus)

抄録

Pressure effects on the twisted intramolecular charge transfer (TICT) phenomenon of 4-(N,N-dimethylamino)benzoate bonded to a polymer side chain (copDB) and its low molecular weight model compound (DBAE) were examined in ethyl acetate. The volume change and the activation volume for the formation of the TICT state were determined to be 2.9 cm3 mol (DBAE) and 5.5 cm3 mol (copDB), respectively. Although the present results for copDB are reasonably explicable as the viscosity effect on the TICT state formation, the effect could not be described by the normal Stokes-Einstein theory but required the Gierer-Wirtz theory.

本文言語English
ページ(範囲)123-127
ページ数5
ジャーナルChemical Physics Letters
135
1-2
DOI
出版ステータスPublished - 1987 3 27
外部発表はい

ASJC Scopus subject areas

  • 物理学および天文学(全般)
  • 物理化学および理論化学

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