Pressure–temperature phase diagram of Ta-H system up to 9 GPa and 600 C

Hiroyuki Saitoh, Shigeyuki Takagi, Toyoto Sato, Shin Ichi Orimo

研究成果査読

抄録

High-pressure hydrogenation behaviors of pure metals have not been investigated exten-sively, although intense research of hydrogenation reactions under high pressure has been conducted to find novel functional hydrides. The former provides us with valuable information for the high-pressure synthesis of novel functional hydrides. A pressure–temperature phase diagram of the Ta–H system has been determined using the in situ synchrotron radiation X-ray diffraction technique below 9 GPa and 600 C in this study. At room temperature, the phase boundary obtained between distorted bcc TaH~1 and hcp TaH~2 was consistent with the previously reported transition pressure. The experimentally obtained Clapeyron slope can be explained via the entropy change caused by hydrogen evolution from TaH~2.

本文言語English
論文番号6719
ジャーナルApplied Sciences (Switzerland)
11
15
DOI
出版ステータスPublished - 2021 8 1

ASJC Scopus subject areas

  • 材料科学(全般)
  • 器械工学
  • 工学(全般)
  • プロセス化学およびプロセス工学
  • コンピュータ サイエンスの応用
  • 流体および伝熱

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