Quantum cutting organic-inorganic nanocomposites

Abdalla M. Darwish, Sergey S. Sarkisov, Simeon Wilson, Eboni Collins, Darayas N. Patel, Paolo Mele, Brent Koplitz

研究成果

抄録

We report on organic-inorganic nanocomposites with combined properties of quantum cutting and down shifting of solar UV spectrum. They cut a single high energy UV photon of solar radiation in two near-IR (NIR) low energy photons and use the energy of the UV photon to produce low energy visible photons. The applications include solar spectrum down-convertors and luminescent solar concentrators (LSCs). The nanocomposites were made of organic hosts filled the nanoparticles of Lanthanide doped fluoride phosphor NaYF4:Yb3+, Er3+. As an organic host for the nanoparticles in an LSC simulator 1-Propanol was used. The particles of the synthesized phosphor powder were ball-milled to an average size of~ 200-nm. The LSC filled with the phosphor nanocolloid produced 130% more electric power than in case of pure 1-Propanol. This effect was not observed when the LSC was illuminated with an incandescent light bulb with no UV component in its radiation spectrum. The LSC performance was thus due to down shifting and quantum cutting of the UV spectral component of solar radiation by the phosphor nanoparticles into visible and NIR radiation matching the spectral response of the silicon PV solar cells. The results are of interest for green solar power.

本文言語English
ホスト出版物のタイトルPhotonic Fiber and Crystal Devices
ホスト出版物のサブタイトルAdvances in Materials and Innovations in Device Applications XV
編集者Shizhuo Yin, Ruyan Guo
出版社SPIE
ISBN(電子版)9781510644908
DOI
出版ステータスPublished - 2021
イベントPhotonic Fiber and Crystal Devices: Advances in Materials and Innovations in Device Applications XV 2021 - San Diego, United States
継続期間: 2021 8 12021 8 5

出版物シリーズ

名前Proceedings of SPIE - The International Society for Optical Engineering
11826
ISSN(印刷版)0277-786X
ISSN(電子版)1996-756X

Conference

ConferencePhotonic Fiber and Crystal Devices: Advances in Materials and Innovations in Device Applications XV 2021
国/地域United States
CitySan Diego
Period21/8/121/8/5

ASJC Scopus subject areas

  • 電子材料、光学材料、および磁性材料
  • 凝縮系物理学
  • コンピュータ サイエンスの応用
  • 応用数学
  • 電子工学および電気工学

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