抄録
The extractions of inert platinum group metals (PGMs) like Ru(III) and Rh(III) are always slow kinetics and efficiency. This research investigated the extraction behaviors of Ru(III) and Rh(III) in HNO3(aq)/1-octanol system with a pyridinediamide. Extraction kinetics of Ru(III) was accelerated by improving temperature, while not efficiency. After adding a hydrophobic anion like Tf2N−, extractability of Ru(III) extraction was promoted to 95% within 3 h at 356 K. More inert PGM like Rh(III) showed similar extraction behavior with Ru(III). Rh(III) extraction was enhanced to 90% within 2 h at 356 K with Tf2N−. A rapid and efficient extraction of inert PGMs was demonstrated from HNO3(aq)/1-octanol.
| 本文言語 | English |
|---|---|
| ページ | 999-1001 |
| ページ数 | 3 |
| 出版ステータス | Published - 2020 1月 1 |
| イベント | 14th International Nuclear Fuel Cycle Conference, GLOBAL 2019 and Light Water Reactor Fuel Performance Conference, TOP FUEL 2019 - Seattle, United States 継続期間: 2019 9月 22 → 2019 9月 27 |
Conference
| Conference | 14th International Nuclear Fuel Cycle Conference, GLOBAL 2019 and Light Water Reactor Fuel Performance Conference, TOP FUEL 2019 |
|---|---|
| 国/地域 | United States |
| City | Seattle |
| Period | 19/9/22 → 19/9/27 |
ASJC Scopus subject areas
- 燃料技術
- 原子力エネルギーおよび原子力工学