Relationship between the mesoporous intermediate layer structure and the gas permeation property of an amorphous silica membrane synthesized by counter diffusion chemical vapor deposition

Takayuki Nagano, Shinji Fujisaki, Koji Sato, Koji Hataya, Yuji Iwamoto, Mikihiro Nomura, Shin Ichi Nakao

研究成果: Article査読

32 被引用数 (Scopus)

抄録

An amorphous silica membrane with an excellent hydrogen/nitrogen (H 2/N2) permselectivity of >10 000 and a He/H2 permselectivity of 11 was successfully synthesized on a γ-alumina (γ-Al2O3)-coated α-alumina (α-Al 2O3) porous support by counter diffusion chemical vapor deposition using tetramethylorthosilicate and oxygen at 873 K. An amorphous silica membrane possessed a high H2 permeance of >1.0 × 10-7 mol·(m2·s·Pa)-1 at ≥773 K. The dominant permeation mechanism for He and H2 at 373-873 K was activated diffusion. On the other hand, that for CO2, Ar, and N2 at 373-673 K was a viscous flow. At ≥673 K, that for CO 2, Ar, and N2 was activated diffusion. H2 permselectivity was markedly affected by the permeation temperature, thickness, and pore size of a γ-Al2O3 mesoporous intermediate layer.

本文言語English
ページ(範囲)71-76
ページ数6
ジャーナルJournal of the American Ceramic Society
91
1
DOI
出版ステータスPublished - 2008 1 1

ASJC Scopus subject areas

  • Ceramics and Composites
  • Materials Chemistry

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