Relayed Proton Brake in N-Pyridyl-2-iso-propylaniline Derivative: Two Brakes with One Proton

Gaku Furukawa, Takeshi Shirai, Yuki Homma, Elsa Caytan, Nicolas Vanthuyne, Daniel Farran, Christian Roussel, Osamu Kitagawa

研究成果: Article査読

2 被引用数 (Scopus)

抄録

The addition of methanesulfonic acid to N-(2,6-dimethylpyridin-4-yl)-N-methyl-2-iso-propylaniline led to the selective protonation of the pyridine nitrogen atom, resulting in a significant deceleration of the rotation rates around both N-pyridyl and N-(i-Pr)phenyl bonds through a relayed brake mechanism.

本文言語English
ページ(範囲)5109-5113
ページ数5
ジャーナルJournal of Organic Chemistry
85
7
DOI
出版ステータスPublished - 2020 4 3

ASJC Scopus subject areas

  • 有機化学

フィンガープリント

「Relayed Proton Brake in N-Pyridyl-2-iso-propylaniline Derivative: Two Brakes with One Proton」の研究トピックを掘り下げます。これらがまとまってユニークなフィンガープリントを構成します。

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