Relayed Proton Brake in N-Pyridyl-2-iso-propylaniline Derivative: Two Brakes with One Proton

Gaku Furukawa, Takeshi Shirai, Yuki Homma, Elsa Caytan, Nicolas Vanthuyne, Daniel Farran, Christian Roussel, Osamu Kitagawa

研究成果: Article

1 引用 (Scopus)

抜粋

The addition of methanesulfonic acid to N-(2,6-dimethylpyridin-4-yl)-N-methyl-2-iso-propylaniline led to the selective protonation of the pyridine nitrogen atom, resulting in a significant deceleration of the rotation rates around both N-pyridyl and N-(i-Pr)phenyl bonds through a relayed brake mechanism.

元の言語English
ページ(範囲)5109-5113
ページ数5
ジャーナルJournal of Organic Chemistry
85
発行部数7
DOI
出版物ステータスPublished - 2020 4 3

ASJC Scopus subject areas

  • Organic Chemistry

フィンガープリント Relayed Proton Brake in N-Pyridyl-2-iso-propylaniline Derivative: Two Brakes with One Proton' の研究トピックを掘り下げます。これらはともに一意のフィンガープリントを構成します。

  • これを引用

    Furukawa, G., Shirai, T., Homma, Y., Caytan, E., Vanthuyne, N., Farran, D., Roussel, C., & Kitagawa, O. (2020). Relayed Proton Brake in N-Pyridyl-2-iso-propylaniline Derivative: Two Brakes with One Proton. Journal of Organic Chemistry, 85(7), 5109-5113. https://doi.org/10.1021/acs.joc.0c00284