Rotational Behavior of N-(5-Substituted-pyrimidin-2-yl)anilines: Relayed Electronic Effect in Two N-Ar Bond Rotations

Daiki Homma, Shuhei Taketani, Takeshi Shirai, Elsa Caytan, Christian Roussel, José Elguero, Ibon Alkorta, Osamu Kitagawa

研究成果: Article査読

抄録

N-Methyl-2-methoxymethylanilines 1 bearing various 5-substituted-pyrimidin-2-yl groups were prepared, and their rotational behaviors were explored in detail. It was revealed that the rotational barriers around two N-Ar bonds increase in proportion to the electron-withdrawing ability of substituents X at the 5-position.

本文言語English
ページ(範囲)8118-8125
ページ数8
ジャーナルJournal of Organic Chemistry
87
12
DOI
出版ステータスPublished - 2022 6月 17

ASJC Scopus subject areas

  • 有機化学

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