Solution-processed VO2-SiO2 composite films with simultaneously enhanced luminous transmittance, solar modulation ability and anti-oxidation property

Lili Zhao, Lei Miao, Chengyan Liu, Chao Li, Toru Asaka, Yipu Kang, Yuji Iwamoto, Sakae Tanemura, Hui Gu, Huirong Su

研究成果: Article査読

68 被引用数 (Scopus)

抄録

Recently, researchers spare no efforts to fabricate desirable vanadium dioxide (VO2) film which provides simultaneously high luminous transmittance and outstanding solar modulation ability, yet progress towards the optimization of one aspect always comes at the expense of the other. Our research devotes to finding a reproducible economic solution-processed strategy for fabricating VO2-SiO2 composite films, with the aim of boosting the performance of both aspects. Compare to VO2 film, an improvement of 18.9% (from 29.6% to 48.5%) in the luminous transmittance as well as an increase of 6.0% (from 9.7% to 15.7%) in solar modulation efficiency is achieved when the molar ratio of Si/V attains 0.8. Based on the effective medium theory, we simulate the optical spectra of the composite films and the best thermochromic property is obtained when the filling factor attains 0.5, which is consistent with the experimental results. Meanwhile, the improvement of chemical stability for the composite film against oxidation has been confirmed. Tungsten is introduced to reduce the phase transition temperature to the ambient temperature, while maintain the thermochromism required for application as smart window. Our research set forth a new avenue in promoting practical applications of VO2-based thermochromic fenestration.

本文言語English
論文番号7000
ジャーナルScientific Reports
4
DOI
出版ステータスPublished - 2014 11 11
外部発表はい

ASJC Scopus subject areas

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