Stereoselective Iodine Atom Transfer [3 + 2] Cycloaddition Reaction with Alkenes Using Unsymmetrical Allylated Active Methine Radicals

Osamu Kitagawa; Shinsaku Miyaji; Chiseko Sakuma; Takeo Taguchi

doi:10.1021/jo035771a

Stereoselective Iodine Atom Transfer [3 + 2] Cycloaddition Reaction with Alkenes Using Unsymmetrical Allylated Active Methine Radicals

Osamu Kitagawa, Shinsaku Miyaji, Chiseko Sakuma, Takeo Taguchi

研究成果: Article › 査読

10 被引用数 (Scopus)

抄録

Treatment of 1-diethylphosphonyl- or 1-phenyl-sulfonyl-2-(iodomethyl)cyclopropane-l-carboxylate with Et₃B leads to an unsymmetrical allylated active methine radical species that gives functionalized cyclopentane derivatives with high stereoselectivity through iodine atom transfer [3 + 2] cycloaddition reaction with alkenes.

本文言語	English
ページ（範囲）	2607-2610
ページ数	4
ジャーナル	Journal of Organic Chemistry
巻	69
号	7
DOI	https://doi.org/10.1021/jo035771a
出版ステータス	Published - 2004 4月 2
外部発表	はい

ASJC Scopus subject areas

有機化学

文献へのアクセス

10.1021/jo035771a

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「Stereoselective Iodine Atom Transfer [3 + 2] Cycloaddition Reaction with Alkenes Using Unsymmetrical Allylated Active Methine Radicals」の研究トピックを掘り下げます。これらがまとまってユニークなフィンガープリントを構成します。

引用スタイル

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