Stereoselective Iodine Atom Transfer [3 + 2] Cycloaddition Reaction with Alkenes Using Unsymmetrical Allylated Active Methine Radicals

Osamu Kitagawa, Shinsaku Miyaji, Chiseko Sakuma, Takeo Taguchi

研究成果: Article

10 引用 (Scopus)

抜粋

Treatment of 1-diethylphosphonyl- or 1-phenyl-sulfonyl-2-(iodomethyl)cyclopropane-l-carboxylate with Et3B leads to an unsymmetrical allylated active methine radical species that gives functionalized cyclopentane derivatives with high stereoselectivity through iodine atom transfer [3 + 2] cycloaddition reaction with alkenes.

元の言語English
ページ(範囲)2607-2610
ページ数4
ジャーナルJournal of Organic Chemistry
69
発行部数7
DOI
出版物ステータスPublished - 2004 4 2
外部発表Yes

ASJC Scopus subject areas

  • Organic Chemistry

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