Stereoselective Iodine Atom Transfer [3 + 2] Cycloaddition Reaction with Alkenes Using Unsymmetrical Allylated Active Methine Radicals

Osamu Kitagawa, Shinsaku Miyaji, Chiseko Sakuma, Takeo Taguchi

研究成果: Article

10 引用 (Scopus)

抄録

Treatment of 1-diethylphosphonyl- or 1-phenyl-sulfonyl-2-(iodomethyl)cyclopropane-l-carboxylate with Et3B leads to an unsymmetrical allylated active methine radical species that gives functionalized cyclopentane derivatives with high stereoselectivity through iodine atom transfer [3 + 2] cycloaddition reaction with alkenes.

元の言語English
ページ（範囲）2607-2610
ページ数4
ジャーナルJournal of Organic Chemistry
巻69
発行部数7
DOI
出版物ステータスPublished - 2004 4 2
外部発表Yes

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Cyclopentanes
Stereoselectivity
Cycloaddition
Alkenes
Iodine
Derivatives
Atoms
cyclopropane

ASJC Scopus subject areas

  • Organic Chemistry

これを引用

Stereoselective Iodine Atom Transfer [3 + 2] Cycloaddition Reaction with Alkenes Using Unsymmetrical Allylated Active Methine Radicals. / Kitagawa, Osamu; Miyaji, Shinsaku; Sakuma, Chiseko; Taguchi, Takeo.

：: Journal of Organic Chemistry, 巻 69, 番号 7, 02.04.2004, p. 2607-2610.

研究成果: Article

Kitagawa, O, Miyaji, S, Sakuma, C & Taguchi, T 2004, 'Stereoselective Iodine Atom Transfer [3 + 2] Cycloaddition Reaction with Alkenes Using Unsymmetrical Allylated Active Methine Radicals', Journal of Organic Chemistry, 巻. 69, 番号 7, pp. 2607-2610. https://doi.org/10.1021/jo035771a
Kitagawa O, Miyaji S, Sakuma C, Taguchi T. Stereoselective Iodine Atom Transfer [3 + 2] Cycloaddition Reaction with Alkenes Using Unsymmetrical Allylated Active Methine Radicals. Journal of Organic Chemistry. 2004 4 2;69(7):2607-2610. https://doi.org/10.1021/jo035771a
Kitagawa, Osamu ; Miyaji, Shinsaku ; Sakuma, Chiseko ; Taguchi, Takeo. / Stereoselective Iodine Atom Transfer [3 + 2] Cycloaddition Reaction with Alkenes Using Unsymmetrical Allylated Active Methine Radicals. ：: Journal of Organic Chemistry. 2004 ; 巻 69, 番号 7. pp. 2607-2610.
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