Structural analysis of multifunctional ionic gels

Kumkum Ahmed, Naufumi Naga, Hidemitsu Furukawa

研究成果: Conference contribution

1 被引用数 (Scopus)

抄録

Ionic liquid (IL) mediated gels commonly known as ion gels or ionic gels have received remarkable attention for their advanced application in electrochemical and electromechanical devices, such as actuators, lithium batteries, electric double-layer capacitors, dye-sensitized solar cells and fuel cells. In this work we focused to determine structural properties of thiol-ene crosslinked gels both in organic solvent dimethyl sulfoxide (DMSO) and IL, 1-butyl-3-methylimidazolium bis(fluorosulfonyl)imide (BMIm FSI) combining multifunctional thiol end-crosslinkers and diacrylate monomer via thiol-ene click reaction. We investigated their mechanical properties and internal structure by estimating mesh chain densities calculated from Young’s modulus compression test and nondestructive scattering method of determining mesh size by scanning microscopic light scattering (SMILS) techniques respectively. The mesh densities of the gels were found to be highly dependent on the functionality of the thiol compound both in IL and conventional solvent, DMSO. Finally, we compared the mesh chain densities determined by the two methods and discussed the assumptions to understand the internal structure of these gels.

本文言語English
ホスト出版物のタイトルECS Transactions
編集者L. Nagahara, G. Milano, Y. Masubuchi, T. Saito, P. Sekhar, S. Bhansali, F. D. Dos Santos, K. Fukushima, T.-Y. Chu, S. Tokito, A. Nakai, T. Shiba, H. Ito, M. Kaltenbrunner, H. Matsui, A. Khosla, H. Furukawa, K. Ito, A. Kakugo, M. White, A. Masuhara, M. Yanagida, T. Yoshida
出版社Electrochemical Society Inc.
ページ427-436
ページ数10
1
ISBN(電子版)9781607688655
DOI
出版ステータスPublished - 2019
外部発表はい
イベント1st International Conference on 4D Materials and Systems, 4DMS 2018 - Yonezawa, Japan
継続期間: 2018 8 262018 8 30

出版物シリーズ

名前ECS Transactions
番号1
88
ISSN(印刷版)1938-6737
ISSN(電子版)1938-5862

Conference

Conference1st International Conference on 4D Materials and Systems, 4DMS 2018
CountryJapan
CityYonezawa
Period18/8/2618/8/30

ASJC Scopus subject areas

  • Engineering(all)

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