抄録
Expanded p-conjugated coordination complexes, [M(L2)2] (M = Cu2+, Pd2+, and Pt2+; L2= dinaphthoylmethanido-), were prepared and the different metal characteristics were found due to the supramolecular associations: [Cu(L2)2] shows a remarkable M2+?p interaction (3.249 Å) inducing the cationicity of Cu2+and the strength of the interactions clearly decreases for the Pd2+and Pt2+ions (3.785 and 4.610 Å), indicating their electron-rich and nucleophilic characteristics.
本文言語 | English |
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ページ(範囲) | 3090-3094 |
ページ数 | 5 |
ジャーナル | CrystEngComm |
巻 | 22 |
号 | 18 |
DOI | |
出版ステータス | Published - 2020 3 14 |
ASJC Scopus subject areas
- Chemistry(all)
- Materials Science(all)
- Condensed Matter Physics