Surface characterization of Miscanthus × giganteus and Willow subjected to torrefaction

Jacek Grams, Marzena Kwapińska, Marcin Jędrzejczyk, Izabela Rzeźnicka, James J. Leahy, Agnieszka M. Ruppert

研究成果: Article査読

11 被引用数 (Scopus)

抄録

The main goal of this work was to determine the differences in the composition of the surface and bulk of lignocellulosic feedstock subjected to torrefaction. Miscanthus × giganteus and Willow were used as widely available types of second generation of biomass. The surface of the samples was primarily characterized by time-of-flight secondary ion mass spectrometry. The bulk of the investigated biomass was analyzed by Fourier transform infrared spectroscopy, thermogravimetry and classical chemical methods. The results obtained show that the destruction of the surface of both Miscanthus × giganteus and Willow begin at lower temperature than that observed for the bulk. Moreover, in the case of Miscanthus × giganteus the possibility of the partial surface decomposition of not only the hemicellulose and cellulose but also lignin structure is pointed out. The observed differences between the behavior of the uppermost and deeper layers of the studied biomass samples indicate that the efficiency of their thermal degradation is different and should be taken into account when discussing the torrefaction process.

本文言語English
ページ(範囲)231-241
ページ数11
ジャーナルJournal of Analytical and Applied Pyrolysis
138
DOI
出版ステータスPublished - 2019 3

ASJC Scopus subject areas

  • 分析化学
  • 燃料技術

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