抄録
We have synthesized and characterized a series of novel compounds of α,α'-bis(aminomethyl)oligothiophenes and their related compounds whose degree of polymerization spans two (dimer) to five (pentamer). The compounds presented in our studies are α,α'-bis[(2,2,5,5-tetramethyl-1-aza-2,5-disilacyclopenthyl)methyl] oligothiophene, α,α'-bis(aminomethyl)oligothiophene dihydrochloride and α,α'- bis(aminomethyl)oligothiophene. These compounds exhibit desired chemical activity while maintaining controllable electronic properties. The synthetic processes of the oligothiophenes are as follows: 2-aminomethylthiophene is first 'protected' and the thiophene rings are coupled using standard Grignard methods. The protected groups are removed at the final stage of the reaction. The compounds show unique properties; for example α,α'-bis(aminomethyl)oligothiophene dihydrochloride is soluble in water. The results of electronic spectra and duration are also presented.
| 元の言語 | English |
|---|---|
| ページ（範囲） | 173-178 |
| ページ数 | 6 |
| ジャーナル | Journal of Heterocyclic Chemistry |
| 巻 | 33 |
| 発行部数 | 1 |
| 出版物ステータス | Published - 1996 |
| 外部発表 | Yes |
Fingerprint
ASJC Scopus subject areas
- Organic Chemistry
これを引用
Synthesis and Characterization of α,α'-Bis(aminomethyl)oligothiophenes and Their Related Compounds. / Muguruma, Hitoshi; Saito, Takashi; Sasaki, Satoshi; Hotta, Shu; Karube, Isao.
：: Journal of Heterocyclic Chemistry, 巻 33, 番号 1, 1996, p. 173-178.研究成果: Article
}
TY - JOUR
T1 - Synthesis and Characterization of α,α'-Bis(aminomethyl)oligothiophenes and Their Related Compounds
AU - Muguruma, Hitoshi
AU - Saito, Takashi
AU - Sasaki, Satoshi
AU - Hotta, Shu
AU - Karube, Isao
PY - 1996
Y1 - 1996
N2 - We have synthesized and characterized a series of novel compounds of α,α'-bis(aminomethyl)oligothiophenes and their related compounds whose degree of polymerization spans two (dimer) to five (pentamer). The compounds presented in our studies are α,α'-bis[(2,2,5,5-tetramethyl-1-aza-2,5-disilacyclopenthyl)methyl] oligothiophene, α,α'-bis(aminomethyl)oligothiophene dihydrochloride and α,α'- bis(aminomethyl)oligothiophene. These compounds exhibit desired chemical activity while maintaining controllable electronic properties. The synthetic processes of the oligothiophenes are as follows: 2-aminomethylthiophene is first 'protected' and the thiophene rings are coupled using standard Grignard methods. The protected groups are removed at the final stage of the reaction. The compounds show unique properties; for example α,α'-bis(aminomethyl)oligothiophene dihydrochloride is soluble in water. The results of electronic spectra and duration are also presented.
AB - We have synthesized and characterized a series of novel compounds of α,α'-bis(aminomethyl)oligothiophenes and their related compounds whose degree of polymerization spans two (dimer) to five (pentamer). The compounds presented in our studies are α,α'-bis[(2,2,5,5-tetramethyl-1-aza-2,5-disilacyclopenthyl)methyl] oligothiophene, α,α'-bis(aminomethyl)oligothiophene dihydrochloride and α,α'- bis(aminomethyl)oligothiophene. These compounds exhibit desired chemical activity while maintaining controllable electronic properties. The synthetic processes of the oligothiophenes are as follows: 2-aminomethylthiophene is first 'protected' and the thiophene rings are coupled using standard Grignard methods. The protected groups are removed at the final stage of the reaction. The compounds show unique properties; for example α,α'-bis(aminomethyl)oligothiophene dihydrochloride is soluble in water. The results of electronic spectra and duration are also presented.
UR - http://www.scopus.com/inward/record.url?scp=0000244229&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=0000244229&partnerID=8YFLogxK
M3 - Article
AN - SCOPUS:0000244229
VL - 33
SP - 173
EP - 178
JO - Journal of Heterocyclic Chemistry
JF - Journal of Heterocyclic Chemistry
SN - 0022-152X
IS - 1
ER -