Synthesis of joint-linker type ionic gels containing imidazole units in the network

N. Naga; T. Ishida; T. Hayakawa

doi:10.1149/08801.0107ecst

Synthesis of joint-linker type ionic gels containing imidazole units in the network

N. Naga, T. Ishida, T. Hayakawa

研究成果: Conference contribution

抄録

Joint-linker type gels have been synthesized by means of thiol-ene reaction of tri-functional thiol and bis-vinylimidazole compounds, or Menschutkin reaction of multi-functional bromomethyl benzene, and bis-imidazole compound in dimethylsulfoxide (DMSO). The gels showed ionic conductivity derived from anions in the linker molecules. The ionic conductivity of the gels decreased with increasing of the monomer concentration. Temperature dependence of the gels was investigated to determine Vogel-Tammann-Fulcher (VTF) equation parameters. The results indicated that increasing of the crosslinking density should prevent the anions from diffusing in the gels due to the increase of activation energy of the ion transport. The gel with bis-vinylimidazole [BF₄] showed higher ionic conductivity than the corresponding gel with [Br] due to higher dissociation the ion carrier. Addition of a protonic solvent, methanol, to DMSO was effective to increase the ionic conductivity.

本文言語	English
ホスト出版物のタイトル	ECS Transactions
編集者	G. Milano, L. Nagahara, A. Kakugo, M. White, T. Shiba, Y. Masubuchi, S. Tokito, K. Fukushima, H. Furukawa, T. Yoshida, A. Khosla, M. Kaltenbrunner, T.-Y. Chu, H. Matsui, F. D. Dos Santos, A. Nakai, M. Yanagida, P. Sekhar, H. Ito, K. Ito, T. Saito, S. Bhansali, A. Masuhara
出版社	Electrochemical Society Inc.
ページ	107-118
ページ数	12
版	1
ISBN（電子版）	9781607688655
DOI	https://doi.org/10.1149/08801.0107ecst
出版ステータス	Published - 2019
イベント	1st International Conference on 4D Materials and Systems, 4DMS 2018 - Yonezawa, Japan 継続期間: 2018 8 26 → 2018 8 30

出版物シリーズ

名前	ECS Transactions
番号	1
巻	88
ISSN（印刷版）	1938-6737
ISSN（電子版）	1938-5862

Conference

Conference	1st International Conference on 4D Materials and Systems, 4DMS 2018
Country	Japan
City	Yonezawa
Period	18/8/26 → 18/8/30

ASJC Scopus subject areas

Engineering(all)

文献へのアクセス

10.1149/08801.0107ecst

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引用スタイル

Naga, N., Ishida, T., & Hayakawa, T. (2019). Synthesis of joint-linker type ionic gels containing imidazole units in the network. In G. Milano, L. Nagahara, A. Kakugo, M. White, T. Shiba, Y. Masubuchi, S. Tokito, K. Fukushima, H. Furukawa, T. Yoshida, A. Khosla, M. Kaltenbrunner, T-Y. Chu, H. Matsui, F. D. Dos Santos, A. Nakai, M. Yanagida, P. Sekhar, H. Ito, K. Ito, T. Saito, S. Bhansali, ... A. Masuhara (Eds.), ECS Transactions (1 ed., pp. 107-118). (ECS Transactions; Vol. 88, No. 1). Electrochemical Society Inc.. https://doi.org/10.1149/08801.0107ecst

Synthesis of joint-linker type ionic gels containing imidazole units in the network. / Naga, N.; Ishida, T.; Hayakawa, T.

ECS Transactions. ed. / G. Milano; L. Nagahara; A. Kakugo; M. White; T. Shiba; Y. Masubuchi; S. Tokito; K. Fukushima; H. Furukawa; T. Yoshida; A. Khosla; M. Kaltenbrunner; T.-Y. Chu; H. Matsui; F. D. Dos Santos; A. Nakai; M. Yanagida; P. Sekhar; H. Ito; K. Ito; T. Saito; S. Bhansali; A. Masuhara. 1. ed. Electrochemical Society Inc., 2019. p. 107-118 (ECS Transactions; Vol. 88, No. 1).

研究成果: Conference contribution

Naga, N, Ishida, T & Hayakawa, T 2019, Synthesis of joint-linker type ionic gels containing imidazole units in the network. in G Milano, L Nagahara, A Kakugo, M White, T Shiba, Y Masubuchi, S Tokito, K Fukushima, H Furukawa, T Yoshida, A Khosla, M Kaltenbrunner, T-Y Chu, H Matsui, FD Dos Santos, A Nakai, M Yanagida, P Sekhar, H Ito, K Ito, T Saito, S Bhansali & A Masuhara (eds), ECS Transactions. 1 edn, ECS Transactions, no. 1, vol. 88, Electrochemical Society Inc., pp. 107-118, 1st International Conference on 4D Materials and Systems, 4DMS 2018, Yonezawa, Japan, 18/8/26. https://doi.org/10.1149/08801.0107ecst

Naga N, Ishida T, Hayakawa T. Synthesis of joint-linker type ionic gels containing imidazole units in the network. In Milano G, Nagahara L, Kakugo A, White M, Shiba T, Masubuchi Y, Tokito S, Fukushima K, Furukawa H, Yoshida T, Khosla A, Kaltenbrunner M, Chu T-Y, Matsui H, Dos Santos FD, Nakai A, Yanagida M, Sekhar P, Ito H, Ito K, Saito T, Bhansali S, Masuhara A, editors, ECS Transactions. 1 ed. Electrochemical Society Inc. 2019. p. 107-118. (ECS Transactions; 1). https://doi.org/10.1149/08801.0107ecst

Naga, N. ; Ishida, T. ; Hayakawa, T. / Synthesis of joint-linker type ionic gels containing imidazole units in the network. ECS Transactions. editor / G. Milano ; L. Nagahara ; A. Kakugo ; M. White ; T. Shiba ; Y. Masubuchi ; S. Tokito ; K. Fukushima ; H. Furukawa ; T. Yoshida ; A. Khosla ; M. Kaltenbrunner ; T.-Y. Chu ; H. Matsui ; F. D. Dos Santos ; A. Nakai ; M. Yanagida ; P. Sekhar ; H. Ito ; K. Ito ; T. Saito ; S. Bhansali ; A. Masuhara. 1. ed. Electrochemical Society Inc., 2019. pp. 107-118 (ECS Transactions; 1).

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