Synthesis of network polymers from multifunctional aromatic thiol compounds

Naofumi Naga, Hiroshi Tanaka, Kazumasa Moriyama

研究成果: Article査読

2 被引用数 (Scopus)

抄録

Network polymers have been synthesized by means of catalyst free thiol-yne reaction of multi-functional aromatic ethynyle and thiol compounds, 1,3,5-triethynylbenzenen (TEB), 1,4-diethynylbenzene (DEB), 1,4-benzenedithiol (BDT) and benzenethiol (BT). The network polymers of TEB/DEB-BDT or TEB-BDT/BT were obtained in good yields. The feed ratio of DEB or BT increased the chloroform solution, fragments, of the network polymers. The fragments of the network polymers showed optical properties derived from conjugation units of phenyl-ethynyl-sulfide. The network polymers have been synthesized by oxidation reaction of multi-functional aromatic thiol compounds, 1,3,5-benzene trithiol (BTT) with BDT or 4,4’-biphenyl dithiol (BPDT), accompanied by formation of disulfide bonds. The BTT network was degradable by a reductant, tris(2-caboxyethyl)phosphine hydrochloride.

本文言語English
ページ(範囲)B3079-B3083
ジャーナルJournal of the Electrochemical Society
166
9
DOI
出版ステータスPublished - 2019

ASJC Scopus subject areas

  • 電子材料、光学材料、および磁性材料
  • 再生可能エネルギー、持続可能性、環境
  • 表面、皮膜および薄膜
  • 電気化学
  • 材料化学

フィンガープリント

「Synthesis of network polymers from multifunctional aromatic thiol compounds」の研究トピックを掘り下げます。これらがまとまってユニークなフィンガープリントを構成します。

引用スタイル