Synthesis of trehalose mimics by bismuth(III) triflate or bis(trifluoromethane)sulfonimide-catalyzed 1-C-methyl-d-hexopyranosylation

Takashi Yamanoi, Ryo Inoue, Sho Matsuda, Kaname Katsuraya, Keita Hamasaki

研究成果: Article

22 引用 (Scopus)

抜粋

We investigated the ketopyranosylation of 2,3,4,6-tetra-O-benzyl-1-C-methyl-d-hexopyranoses with the benzylated d-aldohexopyranoses in order to produce novel non-reducing disaccharides as trehalose mimics. It was found that 5 mol % of bismuth(III) triflate or bis(trifluoromethane)sulfonimide efficiently catalyzed the ketopyranosylation that produced various non-reducing disaccharides.

元の言語English
ページ(範囲)2914-2918
ページ数5
ジャーナルTetrahedron Asymmetry
17
発行部数20
DOI
出版物ステータスPublished - 2006 11 6

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ASJC Scopus subject areas

  • Catalysis
  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Inorganic Chemistry

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