The synthesis of optically active N-C axially chiral tetrahydroquinoline and its response to an acid-accelerated molecular rotor

Yuya Suzuki, Masato Kageyama, Ryuichi Morisawa, Yasuo Dobashi, Hiroshi Hasegawa, Satoshi Yokojima, Osamu Kitagawa

研究成果: Article

8 引用 (Scopus)

抄録

Optically active atropisomeric N-(2,5-di-tert-butylphenyl)-1,2,3,4-tetrahydroquinoline with an N-C chiral axis was prepared via a catalytic enantioselective reaction. The addition of methane sulfonic acid to this axially chiral quinoline dramatically lowered the barrier to rotation around the chiral axis.

元の言語English
ページ(範囲)11229-11232
ページ数4
ジャーナルChemical Communications
51
発行部数56
DOI
出版物ステータスPublished - 2015 7 18

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Sulfonic Acids
Methane
Rotors
Acids
1,2,3,4-tetrahydroquinoline
quinoline

ASJC Scopus subject areas

  • Chemistry(all)
  • Catalysis
  • Ceramics and Composites
  • Electronic, Optical and Magnetic Materials
  • Surfaces, Coatings and Films
  • Materials Chemistry
  • Metals and Alloys

これを引用

The synthesis of optically active N-C axially chiral tetrahydroquinoline and its response to an acid-accelerated molecular rotor. / Suzuki, Yuya; Kageyama, Masato; Morisawa, Ryuichi; Dobashi, Yasuo; Hasegawa, Hiroshi; Yokojima, Satoshi; Kitagawa, Osamu.

:: Chemical Communications, 巻 51, 番号 56, 18.07.2015, p. 11229-11232.

研究成果: Article

Suzuki, Yuya ; Kageyama, Masato ; Morisawa, Ryuichi ; Dobashi, Yasuo ; Hasegawa, Hiroshi ; Yokojima, Satoshi ; Kitagawa, Osamu. / The synthesis of optically active N-C axially chiral tetrahydroquinoline and its response to an acid-accelerated molecular rotor. :: Chemical Communications. 2015 ; 巻 51, 番号 56. pp. 11229-11232.
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AU - Kitagawa, Osamu

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