抄録
Optically active atropisomeric N-(2,5-di-tert-butylphenyl)-1,2,3,4-tetrahydroquinoline with an N-C chiral axis was prepared via a catalytic enantioselective reaction. The addition of methane sulfonic acid to this axially chiral quinoline dramatically lowered the barrier to rotation around the chiral axis.
本文言語 | English |
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ページ(範囲) | 11229-11232 |
ページ数 | 4 |
ジャーナル | Chemical Communications |
巻 | 51 |
号 | 56 |
DOI | |
出版ステータス | Published - 2015 7 18 |
ASJC Scopus subject areas
- Catalysis
- Electronic, Optical and Magnetic Materials
- Ceramics and Composites
- Chemistry(all)
- Surfaces, Coatings and Films
- Metals and Alloys
- Materials Chemistry