Thermal and Electrical Conductivity of Ge1Sb4Te7 Chalcogenide Alloy

Rui Lan, Rie Endo, Masashi Kuwahara, Yoshinao Kobayashi, Masahiro Susa

研究成果: Article査読

4 被引用数 (Scopus)

抄録

The unique properties of the Ge1Sb4Te7 alloy as a chalcogenide make it a good candidate for application in phase-change random access memory as well as thermoelectric materials. The thermal and electrical conductivity of the Ge1Sb4Te7 alloy play an important role in both applications. This work aims to determine the thermal conductivity and electrical resistivity of the Ge1Sb4Te7 alloy as a function of temperature and to discuss the thermal conduction mechanism. Thermal conductivity and electrical resistivity were measured from room temperature to 778 K using the hot strip method and the four-terminal method, respectively. The thermal conductivity of the Ge1Sb4Te7 alloy shows an interesting temperature dependence: it decreases up to about 600 K, and then increases with increasing temperature. The electrical resistivity shows a monotonic increase with increasing temperature. Through a discussion of the thermal conductivity results together with electrical resistivity results, it is proposed that electronic thermal conductivity dominates the thermal conductivity, while the bipolar diffusion contributes to the increase in the thermal conductivity at higher temperatures. The resonance bonding existing in this chalcogenide alloy accounts for the low lattice thermal conductivity.

本文言語English
ページ(範囲)955-960
ページ数6
ジャーナルJournal of Electronic Materials
46
2
DOI
出版ステータスPublished - 2017 2月 1
外部発表はい

ASJC Scopus subject areas

  • 電子材料、光学材料、および磁性材料
  • 凝縮系物理学
  • 電子工学および電気工学
  • 材料化学

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